Electrodeposition of Pt onto RuO 2(110) single-crystal surface

Miomir B. Vukmirovic, Ping Liu, James Muckerman, Radoslav R. Adzic

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

The electrodeposition of Pt on RuO 2(110) from acid solutions of several Pt complexes was studied using programmed potential step or potential sweep methods. The RuO 2(110) single-crystal surface was obtained by gas-phase oxidation of Ru(0001). The electrodeposition process is characterized by a large crystallization overpotential and three-dimensional growth from a Pt adlayer. The mismatch between the RuO 2(110) and Pt lattices is the likely origin of that overpotential. The nucleation is instantaneous, as verified by potential step experiments. The process starts with depositing a 0.25 ML of Pt, with Pt atoms arranged in a c(2 × 2) array, which is followed by the growth of Pt islands and three-dimensional clusters as in the Stranski-Krastanov growth mode. Density functional theory calculations were used to help in elucidating atomically resolved electrochemical scanning tunneling microscopy (ECSTM) images of the initial stages of Pt deposition. A Pt adlayer on RuO 2(110) has lower catalytic activity for the oxygen reduction reaction compared to Pt, which is in agreement with a large calculated upshift of the d-band center of a low-coverage Pt deposit on RuO 2-(110) as well as a lack of the oxygen adsorption in a bridge configuration on that surface.

Original languageEnglish
Pages (from-to)15306-15311
Number of pages6
JournalJournal of Physical Chemistry C
Volume111
Issue number42
DOIs
Publication statusPublished - Oct 25 2007

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Single crystal surfaces
crystal surfaces
Electrodeposition
electrodeposition
single crystals
Oxygen
Scanning tunneling microscopy
oxygen
Crystallization
Density functional theory
catalytic activity
scanning tunneling microscopy
Catalyst activity
Nucleation
Deposits
Gases
deposits
nucleation
crystallization
vapor phases

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Electronic, Optical and Magnetic Materials
  • Surfaces, Coatings and Films
  • Energy(all)

Cite this

Electrodeposition of Pt onto RuO 2(110) single-crystal surface. / Vukmirovic, Miomir B.; Liu, Ping; Muckerman, James; Adzic, Radoslav R.

In: Journal of Physical Chemistry C, Vol. 111, No. 42, 25.10.2007, p. 15306-15311.

Research output: Contribution to journalArticle

Vukmirovic, Miomir B. ; Liu, Ping ; Muckerman, James ; Adzic, Radoslav R. / Electrodeposition of Pt onto RuO 2(110) single-crystal surface. In: Journal of Physical Chemistry C. 2007 ; Vol. 111, No. 42. pp. 15306-15311.
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