Electrodynamics of nonspherical noble metal nanoparticles and nanoparticle aggregates

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Abstract

This article reviews recent advances in the theory of nanoparticle optical spectra using classical electrodynamics. Although Mie theory has dominated work in this field for nearly a century, this theory is limited to spherical particles and spherical shells, and thus it cannot describe many experiments of recent interest to the chemical and biological sensor community in which nonspherical particles, including particles with only C1 symmetry, and particles in asymmetric environments (i.e. on surfaces and in nonspherical aggregates) are studied. There are now several approaches available for describing nonspherical particles, but the majority of recent applications to isolated particles have been done using the finite element discrete dipole approximation (DDA) theory. The review describes several applications of DDA to the determination of extinction spectra, including extensions to describe solvent and substrate effects. We also describe theories of nanoparticle aggregates based on approaches that explicitly describe electromagnetic coupling between the particles, and effective medium approaches for nonspherical aggregates.

Original languageEnglish
Pages (from-to)73-80
Number of pages8
JournalJournal of Molecular Structure: THEOCHEM
Volume573
DOIs
Publication statusPublished - Oct 26 2001

Fingerprint

Metal Nanoparticles
Metal nanoparticles
Electrodynamics
Precious metals
noble metals
electrodynamics
Nanoparticles
Biota
nanoparticles
Electromagnetic Phenomena
Electromagnetic coupling
Approximation theory
dipoles
Sensors
electromagnetic coupling
Substrates
spherical shells
Mie scattering
approximation
Experiments

Keywords

  • Biosensor
  • Discrete dipole approximation
  • Effective medium approximation
  • Electrodynamics
  • Extinction spectrum
  • Nanoparticle

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Computational Theory and Mathematics
  • Atomic and Molecular Physics, and Optics

Cite this

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abstract = "This article reviews recent advances in the theory of nanoparticle optical spectra using classical electrodynamics. Although Mie theory has dominated work in this field for nearly a century, this theory is limited to spherical particles and spherical shells, and thus it cannot describe many experiments of recent interest to the chemical and biological sensor community in which nonspherical particles, including particles with only C1 symmetry, and particles in asymmetric environments (i.e. on surfaces and in nonspherical aggregates) are studied. There are now several approaches available for describing nonspherical particles, but the majority of recent applications to isolated particles have been done using the finite element discrete dipole approximation (DDA) theory. The review describes several applications of DDA to the determination of extinction spectra, including extensions to describe solvent and substrate effects. We also describe theories of nanoparticle aggregates based on approaches that explicitly describe electromagnetic coupling between the particles, and effective medium approaches for nonspherical aggregates.",
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