Electron transfer and multi-electron accumulation in ExBox4+

Scott M. Dyar, Jonathan C. Barnes, Michal Juríček, J. Fraser Stoddart, Dick T Co, Ryan M. Young, Michael R Wasielewski

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

Molecules capable of accepting and storing multiple electrons are crucial components of artificial photosynthetic systems designed to drive catalysts, such as those used to reduce protons to hydrogen. ExBox4+, a boxlike cyclophane comprising two π-electron-poor extended viologen units tethered at both ends by two p-xylylene linkers, has been shown previously to accept an electron through space from a photoexcited guest. Herein is an investigation of an alternate, through-bond intramolecular electron-transfer pathway involving ExBox4+ using a combination of transient absorption and femtosecond stimulated Raman spectroscopy (FSRS). Upon photoexcitation of ExBox 4+, an electron is transferred from one of the p-xylylene linkers to one of the extended viologen units in ca. 240 ps and recombines in ca. 4 ns. A crystal structure of the doubly reduced species ExBox2+ was obtained. From outside the box: A viologen-based cyclophane ExBox4+ is photoexcited revealing a new through-bond pathway for electron transfer to ExBox4+. The solid-state structure with both redox states ExBox 4+ and ExBox2+ present, confirms that transferred electrons cause ExBox2+ to become flattened and form semiquinoidal structures capable of stabilizing unpaired electrons.

Original languageEnglish
Pages (from-to)5371-5375
Number of pages5
JournalAngewandte Chemie - International Edition
Volume53
Issue number21
DOIs
Publication statusPublished - May 19 2014

Fingerprint

Viologens
Electrons
Photoexcitation
Raman spectroscopy
Protons
Hydrogen
Crystal structure
Catalysts
Molecules

Keywords

  • cyclophanes
  • electron transfer
  • ExBox
  • femtochemistry
  • photochemistry

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis

Cite this

Electron transfer and multi-electron accumulation in ExBox4+ . / Dyar, Scott M.; Barnes, Jonathan C.; Juríček, Michal; Stoddart, J. Fraser; Co, Dick T; Young, Ryan M.; Wasielewski, Michael R.

In: Angewandte Chemie - International Edition, Vol. 53, No. 21, 19.05.2014, p. 5371-5375.

Research output: Contribution to journalArticle

Dyar, Scott M. ; Barnes, Jonathan C. ; Juríček, Michal ; Stoddart, J. Fraser ; Co, Dick T ; Young, Ryan M. ; Wasielewski, Michael R. / Electron transfer and multi-electron accumulation in ExBox4+ In: Angewandte Chemie - International Edition. 2014 ; Vol. 53, No. 21. pp. 5371-5375.
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