Electron Transfer-Oxygen Transfer Reactions and Beyond With Polyoxometalates

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The unique ability of H5PV2Mo10O40 to catalyze electron transfer-oxygen transfer oxidations via activation of sulfides, and carbon-hydrogen, carbon-carbon, and carbon metal bonds, is discussed in the context of sustainable transformations of arenes, the deconstruction of carbohydrates to synthesis gas as a liquid fuel precursor and the prospects for hydroxylation of alkanes. Emphasis is placed on the mechanistic aspects of these reactions including isolation and or observation of intermediates, and the importance of solvents on the oxidation potential of H5PV2Mo10O40. Descriptions possible structures of reactive intermediates as deduced from EPR spectroscopy and DFT calculations are also included.

Original languageEnglish
JournalAdvances in Inorganic Chemistry
DOIs
Publication statusAccepted/In press - 2017

Fingerprint

Carbon
Oxygen
Electrons
Oxidation
Hydroxylation
Alkanes
Synthesis gas
Liquid fuels
Discrete Fourier transforms
Paramagnetic resonance
Hydrogen
Metals
Chemical activation
Carbohydrates
Spectroscopy
carbon sulfide

Keywords

  • Catalysis
  • Oxidation
  • Oxygen transfer
  • Polyoxometalate
  • Vanadium

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

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title = "Electron Transfer-Oxygen Transfer Reactions and Beyond With Polyoxometalates",
abstract = "The unique ability of H5PV2Mo10O40 to catalyze electron transfer-oxygen transfer oxidations via activation of sulfides, and carbon-hydrogen, carbon-carbon, and carbon metal bonds, is discussed in the context of sustainable transformations of arenes, the deconstruction of carbohydrates to synthesis gas as a liquid fuel precursor and the prospects for hydroxylation of alkanes. Emphasis is placed on the mechanistic aspects of these reactions including isolation and or observation of intermediates, and the importance of solvents on the oxidation potential of H5PV2Mo10O40. Descriptions possible structures of reactive intermediates as deduced from EPR spectroscopy and DFT calculations are also included.",
keywords = "Catalysis, Oxidation, Oxygen transfer, Polyoxometalate, Vanadium",
author = "Ronny Neumann",
year = "2017",
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language = "English",
journal = "Advances in Inorganic Chemistry",
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T1 - Electron Transfer-Oxygen Transfer Reactions and Beyond With Polyoxometalates

AU - Neumann, Ronny

PY - 2017

Y1 - 2017

N2 - The unique ability of H5PV2Mo10O40 to catalyze electron transfer-oxygen transfer oxidations via activation of sulfides, and carbon-hydrogen, carbon-carbon, and carbon metal bonds, is discussed in the context of sustainable transformations of arenes, the deconstruction of carbohydrates to synthesis gas as a liquid fuel precursor and the prospects for hydroxylation of alkanes. Emphasis is placed on the mechanistic aspects of these reactions including isolation and or observation of intermediates, and the importance of solvents on the oxidation potential of H5PV2Mo10O40. Descriptions possible structures of reactive intermediates as deduced from EPR spectroscopy and DFT calculations are also included.

AB - The unique ability of H5PV2Mo10O40 to catalyze electron transfer-oxygen transfer oxidations via activation of sulfides, and carbon-hydrogen, carbon-carbon, and carbon metal bonds, is discussed in the context of sustainable transformations of arenes, the deconstruction of carbohydrates to synthesis gas as a liquid fuel precursor and the prospects for hydroxylation of alkanes. Emphasis is placed on the mechanistic aspects of these reactions including isolation and or observation of intermediates, and the importance of solvents on the oxidation potential of H5PV2Mo10O40. Descriptions possible structures of reactive intermediates as deduced from EPR spectroscopy and DFT calculations are also included.

KW - Catalysis

KW - Oxidation

KW - Oxygen transfer

KW - Polyoxometalate

KW - Vanadium

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DO - 10.1016/bs.adioch.2016.12.005

M3 - Article

JO - Advances in Inorganic Chemistry

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