Electronic Polarizability as the Fundamental Variable in the Dielectric Properties of Two-Dimensional Materials

Tian Tian, Declan Scullion, Dale Hughes, Lu Hua Li, Chih Jen Shih, Jonathan Coleman, Manish Chhowalla, Elton J.G. Santos

Research output: Contribution to journalArticlepeer-review

14 Citations (Scopus)


The dielectric constant, which defines the polarization of the media, is a key quantity in condensed matter. It determines several electronic and optoelectronic properties important for a plethora of modern technologies from computer memory to field effect transistors and communication circuits. Moreover, the importance of the dielectric constant in describing electromagnetic interactions through screening plays a critical role in understanding fundamental molecular interactions. Here, we show that despite its fundamental transcendence, the dielectric constant does not define unequivocally the dielectric properties of two-dimensional (2D) materials due to the locality of their electrostatic screening. Instead, the electronic polarizability correctly captures the dielectric nature of a 2D material which is united to other physical quantities in an atomically thin layer. We reveal a long-sought universal formalism where electronic, geometrical, and dielectric properties are intrinsically correlated through the polarizability, opening the door to probe quantities yet not directly measurable including the real covalent thickness of a layer. We unify the concept of dielectric properties in any material dimension finding a global dielectric anisotropy index defining their controllability through dimensionality.

Original languageEnglish
Pages (from-to)841-851
Number of pages11
JournalNano letters
Issue number2
Publication statusPublished - Feb 12 2020


  • Dielectric screening
  • dielectric anisotropy
  • electronic polarizability
  • first priciples simulations
  • scaling relation
  • two-dimensionalmaterial

ASJC Scopus subject areas

  • Bioengineering
  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanical Engineering

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