Electronic structure of vinoxy radical CH2CHO

M. Dupuis, J. J. Wendoloski, W. A. Lester

Research output: Contribution to journalArticle

87 Citations (Scopus)

Abstract

Ab initio multiconfiguration Hartree-Fock (MCHF) wave functions have been used to describe the electronic structure of vinoxy radical CH2CHO. The energy difference between the ground 2A″ state and the first excited 2A″ state is found to be 3.22 eV using a double zeta quality basis set, in good agreement with the observed transition at 3.57 eV. In addition, the calculations predict a near infrared electronic transition.

Original languageEnglish
Pages (from-to)488-492
Number of pages5
JournalThe Journal of Chemical Physics
Volume76
Issue number1
DOIs
Publication statusPublished - 1982

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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