Abstract
Redox "B" ess: Rational design of a new series of boron-functionalized NiIII/NiIV-bis (dicarbollide) clusters results in a family of robust and tunable redox shuttles (see diagram; EDG and EWG denote electron-donating and -withdrawing groups, respectively). This offers a means to rationally control the redox properties in dye-sensitized solar cells (DSCs), leading to exceptionally high open-circuit voltages.
Original language | English |
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Pages (from-to) | 5339-5343 |
Number of pages | 5 |
Journal | Angewandte Chemie - International Edition |
Volume | 49 |
Issue number | 31 |
DOIs | |
Publication status | Published - Jul 19 2010 |
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Keywords
- Bis (dicarbollide)s
- Carboranes
- Dye-sensitized solar cells
- Redox shuttles
- Solar cells
ASJC Scopus subject areas
- Chemistry(all)
- Catalysis
Cite this
Electronic tuning of nickel-based bis(dicarbollide) redox shuttles in dye-sensitized solar cells. / Spokoyny, Alexander M.; Li, Tina C.; Farha, Omar K.; Machan, Charles W.; She, Chunxing; Stern, Charlotte L.; Marks, Tobin J; Hupp, Joseph T; Mirkin, Chad A.
In: Angewandte Chemie - International Edition, Vol. 49, No. 31, 19.07.2010, p. 5339-5343.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Electronic tuning of nickel-based bis(dicarbollide) redox shuttles in dye-sensitized solar cells
AU - Spokoyny, Alexander M.
AU - Li, Tina C.
AU - Farha, Omar K.
AU - Machan, Charles W.
AU - She, Chunxing
AU - Stern, Charlotte L.
AU - Marks, Tobin J
AU - Hupp, Joseph T
AU - Mirkin, Chad A.
PY - 2010/7/19
Y1 - 2010/7/19
N2 - Redox "B" ess: Rational design of a new series of boron-functionalized NiIII/NiIV-bis (dicarbollide) clusters results in a family of robust and tunable redox shuttles (see diagram; EDG and EWG denote electron-donating and -withdrawing groups, respectively). This offers a means to rationally control the redox properties in dye-sensitized solar cells (DSCs), leading to exceptionally high open-circuit voltages.
AB - Redox "B" ess: Rational design of a new series of boron-functionalized NiIII/NiIV-bis (dicarbollide) clusters results in a family of robust and tunable redox shuttles (see diagram; EDG and EWG denote electron-donating and -withdrawing groups, respectively). This offers a means to rationally control the redox properties in dye-sensitized solar cells (DSCs), leading to exceptionally high open-circuit voltages.
KW - Bis (dicarbollide)s
KW - Carboranes
KW - Dye-sensitized solar cells
KW - Redox shuttles
KW - Solar cells
UR - http://www.scopus.com/inward/record.url?scp=77954858011&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=77954858011&partnerID=8YFLogxK
U2 - 10.1002/anie.201002181
DO - 10.1002/anie.201002181
M3 - Article
C2 - 20586090
AN - SCOPUS:77954858011
VL - 49
SP - 5339
EP - 5343
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 31
ER -