Electrophilic ligand abstraction from electron-rich iridium(I) complexes with Me3SiOTf; evidence for direct ligand attack

Michael Aizenberg; David Milstein

doi:10.1039/C39940000411

Electrophilic ligand abstraction from electron-rich iridium(I) complexes with Me₃SiOTf; evidence for direct ligand attack

Michael Aizenberg, David Milstein

Weizmann Institute of Science, Israel

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

Me₃SiOTf (Tf = CF₃SO₂) is a useful reagent for electrophilic abstraction reactions involving electron-rich complexes RlrL_n (R = H, Cl, Me, Ph; L = PMe₃, PEt₃); direct external attack of Me₃Si⁺ on R is probably involved.

Original language	English
Pages (from-to)	411-412
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	4
DOIs	https://doi.org/10.1039/C39940000411
Publication status	Published - 1994

ASJC Scopus subject areas

Molecular Medicine

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10.1039/C39940000411

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title = "Electrophilic ligand abstraction from electron-rich iridium(I) complexes with Me3SiOTf; evidence for direct ligand attack",

abstract = "Me3SiOTf (Tf = CF3SO2) is a useful reagent for electrophilic abstraction reactions involving electron-rich complexes RlrLn (R = H, Cl, Me, Ph; L = PMe3, PEt3); direct external attack of Me3Si+ on R is probably involved.",

author = "Michael Aizenberg and David Milstein",

year = "1994",

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AB - Me3SiOTf (Tf = CF3SO2) is a useful reagent for electrophilic abstraction reactions involving electron-rich complexes RlrLn (R = H, Cl, Me, Ph; L = PMe3, PEt3); direct external attack of Me3Si+ on R is probably involved.

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