Electrophilic ligand abstraction from electron-rich iridium(I) complexes with Me3SiOTf; evidence for direct ligand attack

Michael Aizenberg, David Milstein

Research output: Contribution to journal › Article

14 Citations (Scopus)

Abstract

Me3SiOTf (Tf = CF3SO2) is a useful reagent for electrophilic abstraction reactions involving electron-rich complexes RlrLn (R = H, Cl, Me, Ph; L = PMe3, PEt3); direct external attack of Me3Si+ on R is probably involved.

Original languageEnglish
Pages (from-to)411-412
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number4
DOIs
Publication statusPublished - 1994

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Iridium
Ligands
Electrons

ASJC Scopus subject areas

  • Molecular Medicine

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Electrophilic ligand abstraction from electron-rich iridium(I) complexes with Me3SiOTf; evidence for direct ligand attack. / Aizenberg, Michael; Milstein, David.

In: Journal of the Chemical Society, Chemical Communications, No. 4, 1994, p. 411-412.

Research output: Contribution to journal › Article

Aizenberg, M & Milstein, D 1994, 'Electrophilic ligand abstraction from electron-rich iridium(I) complexes with Me3SiOTf; evidence for direct ligand attack', Journal of the Chemical Society, Chemical Communications, no. 4, pp. 411-412. https://doi.org/10.1039/C39940000411
Aizenberg M, Milstein D. Electrophilic ligand abstraction from electron-rich iridium(I) complexes with Me3SiOTf; evidence for direct ligand attack. Journal of the Chemical Society, Chemical Communications. 1994;(4):411-412. https://doi.org/10.1039/C39940000411
Aizenberg, Michael ; Milstein, David. / Electrophilic ligand abstraction from electron-rich iridium(I) complexes with Me3SiOTf; evidence for direct ligand attack. In: Journal of the Chemical Society, Chemical Communications. 1994 ; No. 4. pp. 411-412.
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