Electrophilic ligand abstraction from electron-rich iridium(I) complexes with Me3SiOTf; evidence for direct ligand attack

Michael Aizenberg; David Milstein

doi:10.1039/C39940000411

Electrophilic ligand abstraction from electron-rich iridium(I) complexes with Me₃SiOTf; evidence for direct ligand attack

Michael Aizenberg, David Milstein

Weizmann Institute of Science, Israel

Research output: Contribution to journal › Article

14 Citations (Scopus)

Abstract

Me₃SiOTf (Tf = CF₃SO₂) is a useful reagent for electrophilic abstraction reactions involving electron-rich complexes RlrL_n (R = H, Cl, Me, Ph; L = PMe₃, PEt₃); direct external attack of Me₃Si⁺ on R is probably involved.

Original language	English
Pages (from-to)	411-412
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	4
DOIs	https://doi.org/10.1039/C39940000411
Publication status	Published - 1994

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ASJC Scopus subject areas

Molecular Medicine

Cite this

Aizenberg, M., & Milstein, D. (1994). Electrophilic ligand abstraction from electron-rich iridium(I) complexes with Me₃SiOTf; evidence for direct ligand attack. Journal of the Chemical Society, Chemical Communications, (4), 411-412. https://doi.org/10.1039/C39940000411

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Access to Document

10.1039/C39940000411