Abstract
Because of their efficient energy-transport properties, porphyrin-based metal-organic frameworks (MOFs) are attractive compounds for solar photochemistry applications. However, their absorption bands provide limited coverage in the visible spectral range for light-harvesting applications. We report here the functionalization of porphyrin-based MOFs with CdSe/ZnS core/shell quantum dots (QDs) for the enhancement of light harvesting via energy transfer from the QDs to the MOFs. The broad absorption band of the QDs in the visible region offers greater coverage of the solar spectrum by QD-MOF hybrid structures. We show through time-resolved emission studies that photoexcitation of the QDs is followed by energy transfer to the MOFs with efficiencies of more than 80%. This sensitization approach can result in a >50% increase in the number of photons harvested by a single monolayer MOF structure with a monolayer of QDs on the surface of the MOF.
| Original language | English |
|---|---|
| Pages (from-to) | 955-958 |
| Number of pages | 4 |
| Journal | Journal of the American Chemical Society |
| Volume | 135 |
| Issue number | 3 |
| DOIs | |
| Publication status | Published - Jan 23 2013 |
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ASJC Scopus subject areas
- Chemistry(all)
- Catalysis
- Biochemistry
- Colloid and Surface Chemistry
Cite this
Energy transfer from quantum dots to metal-organic frameworks for enhanced light harvesting. / Jin, Shengye; Son, Ho Jin; Farha, Omar K.; Wiederrecht, Gary P.; Hupp, Joseph T.
In: Journal of the American Chemical Society, Vol. 135, No. 3, 23.01.2013, p. 955-958.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Energy transfer from quantum dots to metal-organic frameworks for enhanced light harvesting
AU - Jin, Shengye
AU - Son, Ho Jin
AU - Farha, Omar K.
AU - Wiederrecht, Gary P.
AU - Hupp, Joseph T
PY - 2013/1/23
Y1 - 2013/1/23
N2 - Because of their efficient energy-transport properties, porphyrin-based metal-organic frameworks (MOFs) are attractive compounds for solar photochemistry applications. However, their absorption bands provide limited coverage in the visible spectral range for light-harvesting applications. We report here the functionalization of porphyrin-based MOFs with CdSe/ZnS core/shell quantum dots (QDs) for the enhancement of light harvesting via energy transfer from the QDs to the MOFs. The broad absorption band of the QDs in the visible region offers greater coverage of the solar spectrum by QD-MOF hybrid structures. We show through time-resolved emission studies that photoexcitation of the QDs is followed by energy transfer to the MOFs with efficiencies of more than 80%. This sensitization approach can result in a >50% increase in the number of photons harvested by a single monolayer MOF structure with a monolayer of QDs on the surface of the MOF.
AB - Because of their efficient energy-transport properties, porphyrin-based metal-organic frameworks (MOFs) are attractive compounds for solar photochemistry applications. However, their absorption bands provide limited coverage in the visible spectral range for light-harvesting applications. We report here the functionalization of porphyrin-based MOFs with CdSe/ZnS core/shell quantum dots (QDs) for the enhancement of light harvesting via energy transfer from the QDs to the MOFs. The broad absorption band of the QDs in the visible region offers greater coverage of the solar spectrum by QD-MOF hybrid structures. We show through time-resolved emission studies that photoexcitation of the QDs is followed by energy transfer to the MOFs with efficiencies of more than 80%. This sensitization approach can result in a >50% increase in the number of photons harvested by a single monolayer MOF structure with a monolayer of QDs on the surface of the MOF.
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U2 - 10.1021/ja3097114
DO - 10.1021/ja3097114
M3 - Article
C2 - 23293894
AN - SCOPUS:84872760479
VL - 135
SP - 955
EP - 958
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 3
ER -