Enhanced activity of manganese(III) porphyrin epoxidation catalysts through supramolecular complexation

Melissa L. Merlau, William J. Grande, Sonbinh T. Nguyen, Joseph T Hupp

Research output: Contribution to journalArticle

47 Citations (Scopus)

Abstract

Several manganese(III) porphyrins showed significantly increased turnover-numbers for the catalytic epoxidation of styrene upon addition of bulky Lewis acids such as ZnTPP and MgTPP (TPP = tetraphenylporphyrin). Catalytic enhancement of two- to four-fold, depending on the additive, was observed with a manganese porphyrin beating bis-pyridyl groups. The enhancement is primarily attributed to the formation of a coordination trimer, which provides steric protection of the catalyst from bimolecular decomposition. In the absence of coordinating pyridyl moieties on the ligand framework, less significant enhancement is observed; the residual enhancement is speculatively ascribed to the protection of the active manganese-oxo intermediate through direct catalytic site coordination. Finally, in several cases, the addition of Lewis acids also led to the regeneration of deactivated catalysts and full recovery of the original catalytic activity. (C) 2000 Elsevier Science B.V.

Original languageEnglish
Pages (from-to)79-84
Number of pages6
JournalJournal of Molecular Catalysis A: Chemical
Volume156
Issue number1-2
DOIs
Publication statusPublished - May 20 2000

Fingerprint

Lewis Acids
epoxidation
Epoxidation
Porphyrins
Manganese
Complexation
porphyrins
manganese
catalysts
Catalysts
Styrene
augmentation
Catalyst activity
Acids
Ligands
Decomposition
Recovery
acids
trimers
regeneration

Keywords

  • Catalytic epoxidation
  • Manganese
  • Porphyrins
  • Supramolecular chemistry

ASJC Scopus subject areas

  • Catalysis
  • Process Chemistry and Technology

Cite this

Enhanced activity of manganese(III) porphyrin epoxidation catalysts through supramolecular complexation. / Merlau, Melissa L.; Grande, William J.; Nguyen, Sonbinh T.; Hupp, Joseph T.

In: Journal of Molecular Catalysis A: Chemical, Vol. 156, No. 1-2, 20.05.2000, p. 79-84.

Research output: Contribution to journalArticle

Merlau, Melissa L. ; Grande, William J. ; Nguyen, Sonbinh T. ; Hupp, Joseph T. / Enhanced activity of manganese(III) porphyrin epoxidation catalysts through supramolecular complexation. In: Journal of Molecular Catalysis A: Chemical. 2000 ; Vol. 156, No. 1-2. pp. 79-84.
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