Enhanced binding affinity, remarkable selectivity, and high capacity of CO 2 by dual functionalization of a rht-type metal-organic framework

Baiyan Li; Zhijuan Zhang; Yi Li; Kexin Yao; Yihan Zhu; Zhiyong Deng; Fen Yang; Xiaojing Zhou; Guanghua Li; Haohan Wu; Nour Nijem; Yves J. Chabal; Zhiping Lai; Yu Han; Zhan Shi; Shouhua Feng; Jing Li

doi:10.1002/anie.201105966

Enhanced binding affinity, remarkable selectivity, and high capacity of CO ₂ by dual functionalization of a rht-type metal-organic framework

Baiyan Li, Zhijuan Zhang, Yi Li, Kexin Yao, Yihan Zhu, Zhiyong Deng, Fen Yang, Xiaojing Zhou, Guanghua Li, Haohan Wu, Nour Nijem, Yves J. Chabal, Zhiping Lai, Yu Han, Zhan Shi, Shouhua Feng, Jing Li

Rutgers University

Research output: Contribution to journal › Article › peer-review

354 Citations (Scopus)

Abstract

Open and friendly: The smallest member of the rht-type metal-organic frameworks (MOFs, see picture) constructed by a hexacarboxylate ligand with a nitrogen-rich imino triazine backbone shows a significantly enhanced gas binding affinity relative to all other isoreticular rht-type MOFs. The high adsorption capacity and remarkable selectivity of CO ₂ are attributed to the high density of open metal and Lewis basic sites in the framework.

Original language	English
Pages (from-to)	1412-1415
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	51
Issue number	6
DOIs	https://doi.org/10.1002/anie.201105966
Publication status	Published - Feb 6 2012

Keywords

Lewis basic sites
carbon dioxide capture
gas separation
metal-organic frameworks
open metal sites

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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Li, B., Zhang, Z., Li, Y., Yao, K., Zhu, Y., Deng, Z., Yang, F., Zhou, X., Li, G., Wu, H., Nijem, N., Chabal, Y. J., Lai, Z., Han, Y., Shi, Z., Feng, S., & Li, J. (2012). Enhanced binding affinity, remarkable selectivity, and high capacity of CO ₂ by dual functionalization of a rht-type metal-organic framework. Angewandte Chemie - International Edition, 51(6), 1412-1415. https://doi.org/10.1002/anie.201105966

Enhanced binding affinity, remarkable selectivity, and high capacity of CO ₂ by dual functionalization of a rht-type metal-organic framework. / Li, Baiyan; Zhang, Zhijuan; Li, Yi; Yao, Kexin; Zhu, Yihan; Deng, Zhiyong; Yang, Fen; Zhou, Xiaojing; Li, Guanghua; Wu, Haohan; Nijem, Nour; Chabal, Yves J.; Lai, Zhiping; Han, Yu; Shi, Zhan; Feng, Shouhua; Li, Jing.

In: Angewandte Chemie - International Edition, Vol. 51, No. 6, 06.02.2012, p. 1412-1415.

Research output: Contribution to journal › Article › peer-review

Li, B, Zhang, Z, Li, Y, Yao, K, Zhu, Y, Deng, Z, Yang, F, Zhou, X, Li, G, Wu, H, Nijem, N, Chabal, YJ, Lai, Z, Han, Y, Shi, Z, Feng, S & Li, J 2012, 'Enhanced binding affinity, remarkable selectivity, and high capacity of CO ₂ by dual functionalization of a rht-type metal-organic framework', Angewandte Chemie - International Edition, vol. 51, no. 6, pp. 1412-1415. https://doi.org/10.1002/anie.201105966

Li, Baiyan ; Zhang, Zhijuan ; Li, Yi ; Yao, Kexin ; Zhu, Yihan ; Deng, Zhiyong ; Yang, Fen ; Zhou, Xiaojing ; Li, Guanghua ; Wu, Haohan ; Nijem, Nour ; Chabal, Yves J. ; Lai, Zhiping ; Han, Yu ; Shi, Zhan ; Feng, Shouhua ; Li, Jing. / Enhanced binding affinity, remarkable selectivity, and high capacity of CO ₂ by dual functionalization of a rht-type metal-organic framework. In: Angewandte Chemie - International Edition. 2012 ; Vol. 51, No. 6. pp. 1412-1415.

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