Enhanced gas sorption properties and unique behavior toward liquid water in a pillared-paddlewheel metal-organic framework transmetalated with Ni(II)

Olga Karagiaridi, Wojciech Bury, David Fairen-Jimenez, Christopher E. Wilmer, Amy A. Sarjeant, Joseph T. Hupp, Omar K. Farha

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

The synthesis of a permanently porous pillared-paddlewheel metal-organic framework (MOF) was achieved through transmetalation of Zn(II) with Ni(II). The MOF can be treated with liquid water, leading to the reversible displacement of 50% of its pillars by water molecules and resulting in a most unusual crystalline and permanently porous structure.

Original languageEnglish
Pages (from-to)10432-10436
Number of pages5
JournalInorganic Chemistry
Volume53
Issue number19
DOIs
Publication statusPublished - Oct 6 2014

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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