Enhanced gas sorption properties and unique behavior toward liquid water in a pillared-paddlewheel metal-organic framework transmetalated with Ni(II)

Olga Karagiaridi, Wojciech Bury, David Fairen-Jimenez, Christopher E. Wilmer, Amy A. Sarjeant, Joseph T Hupp, Omar K. Farha

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

The synthesis of a permanently porous pillared-paddlewheel metal-organic framework (MOF) was achieved through transmetalation of Zn(II) with Ni(II). The MOF can be treated with liquid water, leading to the reversible displacement of 50% of its pillars by water molecules and resulting in a most unusual crystalline and permanently porous structure.

Original languageEnglish
Pages (from-to)10432-10436
Number of pages5
JournalInorganic Chemistry
Volume53
Issue number19
DOIs
Publication statusPublished - Oct 6 2014

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sorption
Sorption
Gases
Metals
Water
Liquids
liquids
gases
metals
water
Crystalline materials
Molecules
synthesis
molecules

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry

Cite this

Enhanced gas sorption properties and unique behavior toward liquid water in a pillared-paddlewheel metal-organic framework transmetalated with Ni(II). / Karagiaridi, Olga; Bury, Wojciech; Fairen-Jimenez, David; Wilmer, Christopher E.; Sarjeant, Amy A.; Hupp, Joseph T; Farha, Omar K.

In: Inorganic Chemistry, Vol. 53, No. 19, 06.10.2014, p. 10432-10436.

Research output: Contribution to journalArticle

Karagiaridi, Olga ; Bury, Wojciech ; Fairen-Jimenez, David ; Wilmer, Christopher E. ; Sarjeant, Amy A. ; Hupp, Joseph T ; Farha, Omar K. / Enhanced gas sorption properties and unique behavior toward liquid water in a pillared-paddlewheel metal-organic framework transmetalated with Ni(II). In: Inorganic Chemistry. 2014 ; Vol. 53, No. 19. pp. 10432-10436.
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