Enhanced regioselectivity of rhodium-catalysed alkene hydroboration in supercritical carbon dioxide

Charles A G Carter, R. Thomas Baker, Steven P. Nolan, William Tumas

Research output: Contribution to journalArticle

63 Citations (Scopus)

Abstract

Catalysed alkene hydroboration proceeds in supercritical CO2 with several rhodium(I) complexes using tunable fluorinated ligands and shows higher regioselectivity relative to tetrahydrofuran or perfluoromethylcyclohexane.

Original languageEnglish
Pages (from-to)347-348
Number of pages2
JournalChemical Communications
Issue number5
Publication statusPublished - Mar 7 2000

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Regioselectivity
Rhodium
Alkenes
Carbon Dioxide
Olefins
Carbon dioxide
Ligands
perfluoromethylcyclohexane
tetrahydrofuran

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Enhanced regioselectivity of rhodium-catalysed alkene hydroboration in supercritical carbon dioxide. / Carter, Charles A G; Baker, R. Thomas; Nolan, Steven P.; Tumas, William.

In: Chemical Communications, No. 5, 07.03.2000, p. 347-348.

Research output: Contribution to journalArticle

Carter, Charles A G ; Baker, R. Thomas ; Nolan, Steven P. ; Tumas, William. / Enhanced regioselectivity of rhodium-catalysed alkene hydroboration in supercritical carbon dioxide. In: Chemical Communications. 2000 ; No. 5. pp. 347-348.
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