Enhanced regioselectivity of rhodium-catalysed alkene hydroboration in supercritical carbon dioxide

Charles A.G. Carter; R. Thomas Baker; Steven P. Nolan; William Tumas

doi:10.1039/a909636a

Enhanced regioselectivity of rhodium-catalysed alkene hydroboration in supercritical carbon dioxide

Charles A.G. Carter, R. Thomas Baker, Steven P. Nolan, William Tumas

National Renewable Energy Laboratory

Research output: Contribution to journal › Article › peer-review

64 Citations (Scopus)

Abstract

Catalysed alkene hydroboration proceeds in supercritical CO₂ with several rhodium(I) complexes using tunable fluorinated ligands and shows higher regioselectivity relative to tetrahydrofuran or perfluoromethylcyclohexane.

Original language	English
Pages (from-to)	347-348
Number of pages	2
Journal	Chemical Communications
Issue number	5
DOIs	https://doi.org/10.1039/a909636a
Publication status	Published - Mar 7 2000

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Enhanced regioselectivity of rhodium-catalysed alkene hydroboration in supercritical carbon dioxide",

abstract = "Catalysed alkene hydroboration proceeds in supercritical CO2 with several rhodium(I) complexes using tunable fluorinated ligands and shows higher regioselectivity relative to tetrahydrofuran or perfluoromethylcyclohexane.",

author = "Carter, {Charles A.G.} and Baker, {R. Thomas} and Nolan, {Steven P.} and William Tumas",

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