Abstract
The splitting of water into molecular hydrogen and oxygen with the use of renewable solar energy is considered one of the most promising routes to yield sustainable fuel. Herein, we report the H2 evolution performance of gallium doped TiO2 photocatalysts with varying degrees of Ga dopant. The gallium(iii) ions induced significant changes in the structural, textural and electronic properties of TiO2 nanoparticles, resulting in remarkably enhanced photocatalytic activity and good stability for H2 production. Ga3+ ions can act as hole traps that enable a large number of excited electrons to migrate towards the TiO2 surface, thereby facilitating electron transfer and charge separation. Additionally, the cationic dopant and its induced defects might introduce a mid-gap state, promoting electron migration and prolonging the lifetime of charge carrier pairs. We have discovered that the optimal Ga dopant concentration was 3.125 at% and that the incorporation of platinum (0.5 wt%) as a co-catalyst further improved the H2 evolution rate up to 5722 μmol g-1 h-1. Pt not only acts as an electron sink, drastically increasing the electron/hole pair lifetime, but it also creates an intimate contact at the heterojunction between Pt and Ga-TiO2, thus improving the interfacial electron transfer process. These catalyst design strategies provide new ways of designing transition metal photocatalysts that improve green fuel production from renewable solar energy and water.
| Original language | English |
|---|---|
| Pages (from-to) | 2104-2112 |
| Number of pages | 9 |
| Journal | Physical Chemistry Chemical Physics |
| Volume | 20 |
| Issue number | 3 |
| DOIs | |
| Publication status | Published - Jan 1 2018 |
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ASJC Scopus subject areas
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry
Cite this
Enhanced, robust light-driven H2 generation by gallium-doped titania nanoparticles. / Luo, Si; Nguyen-Phan, Thuy Duong; Vovchok, Dimitriy; Waluyo, Iradwikanari; Palomino, Robert M.; Gamalski, Andrew D.; Barrio, Laura; Xu, Wenqian; Polyansky, Dmitry; Rodriguez, José A.; Senanayake, Sanjaya D.
In: Physical Chemistry Chemical Physics, Vol. 20, No. 3, 01.01.2018, p. 2104-2112.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Enhanced, robust light-driven H2 generation by gallium-doped titania nanoparticles
AU - Luo, Si
AU - Nguyen-Phan, Thuy Duong
AU - Vovchok, Dimitriy
AU - Waluyo, Iradwikanari
AU - Palomino, Robert M.
AU - Gamalski, Andrew D.
AU - Barrio, Laura
AU - Xu, Wenqian
AU - Polyansky, Dmitry
AU - Rodriguez, José A.
AU - Senanayake, Sanjaya D.
PY - 2018/1/1
Y1 - 2018/1/1
N2 - The splitting of water into molecular hydrogen and oxygen with the use of renewable solar energy is considered one of the most promising routes to yield sustainable fuel. Herein, we report the H2 evolution performance of gallium doped TiO2 photocatalysts with varying degrees of Ga dopant. The gallium(iii) ions induced significant changes in the structural, textural and electronic properties of TiO2 nanoparticles, resulting in remarkably enhanced photocatalytic activity and good stability for H2 production. Ga3+ ions can act as hole traps that enable a large number of excited electrons to migrate towards the TiO2 surface, thereby facilitating electron transfer and charge separation. Additionally, the cationic dopant and its induced defects might introduce a mid-gap state, promoting electron migration and prolonging the lifetime of charge carrier pairs. We have discovered that the optimal Ga dopant concentration was 3.125 at% and that the incorporation of platinum (0.5 wt%) as a co-catalyst further improved the H2 evolution rate up to 5722 μmol g-1 h-1. Pt not only acts as an electron sink, drastically increasing the electron/hole pair lifetime, but it also creates an intimate contact at the heterojunction between Pt and Ga-TiO2, thus improving the interfacial electron transfer process. These catalyst design strategies provide new ways of designing transition metal photocatalysts that improve green fuel production from renewable solar energy and water.
AB - The splitting of water into molecular hydrogen and oxygen with the use of renewable solar energy is considered one of the most promising routes to yield sustainable fuel. Herein, we report the H2 evolution performance of gallium doped TiO2 photocatalysts with varying degrees of Ga dopant. The gallium(iii) ions induced significant changes in the structural, textural and electronic properties of TiO2 nanoparticles, resulting in remarkably enhanced photocatalytic activity and good stability for H2 production. Ga3+ ions can act as hole traps that enable a large number of excited electrons to migrate towards the TiO2 surface, thereby facilitating electron transfer and charge separation. Additionally, the cationic dopant and its induced defects might introduce a mid-gap state, promoting electron migration and prolonging the lifetime of charge carrier pairs. We have discovered that the optimal Ga dopant concentration was 3.125 at% and that the incorporation of platinum (0.5 wt%) as a co-catalyst further improved the H2 evolution rate up to 5722 μmol g-1 h-1. Pt not only acts as an electron sink, drastically increasing the electron/hole pair lifetime, but it also creates an intimate contact at the heterojunction between Pt and Ga-TiO2, thus improving the interfacial electron transfer process. These catalyst design strategies provide new ways of designing transition metal photocatalysts that improve green fuel production from renewable solar energy and water.
UR - http://www.scopus.com/inward/record.url?scp=85040948691&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85040948691&partnerID=8YFLogxK
U2 - 10.1039/c7cp04155a
DO - 10.1039/c7cp04155a
M3 - Article
AN - SCOPUS:85040948691
VL - 20
SP - 2104
EP - 2112
JO - Physical Chemistry Chemical Physics
JF - Physical Chemistry Chemical Physics
SN - 1463-9076
IS - 3
ER -