Enhancing heterogeneous catalysis through cooperative hybrid organic-inorganic interfaces

Justin M. Notestein, Alexander Katz

Research output: Contribution to journalArticle

197 Citations (Scopus)

Abstract

Active-site/surface cooperativity can enhance heterogeneous organic and organometallic catalysis. We review the powerful role of the solid surface in this context for generating local acidity and, as an inner-sphere ligand, for stabilizing immobilized supramolecular assemblies and unsaturated organometallic complexes that are often unstable in solution.

Original languageEnglish
Pages (from-to)3954-3965
Number of pages12
JournalChemistry - A European Journal
Volume12
Issue number15
DOIs
Publication statusPublished - May 15 2006

Keywords

  • Cooperativity
  • Enantioselectivity
  • Heterogeneous catalysis
  • Organic-inorganic hybrid composites
  • Surface chemistry

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

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