Abstract
Recording the evolution of concentration profiles in nanoporous materials opens a new field of diffusion research with particle ensembles. The technique is based on the complementary application of interference microscopy and IR micro-imaging. Combining the virtues of diffusion measurements with solids and fluids, it provides information of unprecedented wealth and visual power on transport phenomena in molecular ensembles. These phenomena include the diverging uptake and release patterns for concentration-dependent diffusivities, the mechanisms of mass transfer at the fluid-solid interface and opposing tendencies in local and global concentration evolution
| Original language | English |
|---|---|
| Pages (from-to) | 2623-2627 |
| Number of pages | 5 |
| Journal | ChemPhysChem |
| Volume | 10 |
| Issue number | 15 |
| DOIs | |
| Publication status | Published - Oct 19 2009 |
Fingerprint
Keywords
- Diffusion
- Metal-organic frameworks
- Nanoporous materials
- Surface permeation
- Zeolites
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Atomic and Molecular Physics, and Optics
Cite this
Ensemble measurement of diffusion : Novel beauty and evidence. / Chmelik, Christian; Heinke, Lars; Kortunov, Pavel; Li, Jing; Olson, David; Tzoulaki, Despina; Weitkamp, Jens; Kärger, Jörg.
In: ChemPhysChem, Vol. 10, No. 15, 19.10.2009, p. 2623-2627.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Ensemble measurement of diffusion
T2 - Novel beauty and evidence
AU - Chmelik, Christian
AU - Heinke, Lars
AU - Kortunov, Pavel
AU - Li, Jing
AU - Olson, David
AU - Tzoulaki, Despina
AU - Weitkamp, Jens
AU - Kärger, Jörg
PY - 2009/10/19
Y1 - 2009/10/19
N2 - Recording the evolution of concentration profiles in nanoporous materials opens a new field of diffusion research with particle ensembles. The technique is based on the complementary application of interference microscopy and IR micro-imaging. Combining the virtues of diffusion measurements with solids and fluids, it provides information of unprecedented wealth and visual power on transport phenomena in molecular ensembles. These phenomena include the diverging uptake and release patterns for concentration-dependent diffusivities, the mechanisms of mass transfer at the fluid-solid interface and opposing tendencies in local and global concentration evolution
AB - Recording the evolution of concentration profiles in nanoporous materials opens a new field of diffusion research with particle ensembles. The technique is based on the complementary application of interference microscopy and IR micro-imaging. Combining the virtues of diffusion measurements with solids and fluids, it provides information of unprecedented wealth and visual power on transport phenomena in molecular ensembles. These phenomena include the diverging uptake and release patterns for concentration-dependent diffusivities, the mechanisms of mass transfer at the fluid-solid interface and opposing tendencies in local and global concentration evolution
KW - Diffusion
KW - Metal-organic frameworks
KW - Nanoporous materials
KW - Surface permeation
KW - Zeolites
UR - http://www.scopus.com/inward/record.url?scp=70350126435&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=70350126435&partnerID=8YFLogxK
U2 - 10.1002/cphc.200900489
DO - 10.1002/cphc.200900489
M3 - Article
C2 - 19750534
AN - SCOPUS:70350126435
VL - 10
SP - 2623
EP - 2627
JO - ChemPhysChem
JF - ChemPhysChem
SN - 1439-4235
IS - 15
ER -