Abstract
The dependence of rate, entropy of activation, and (1H/ 2H) kinetic isotope effect for H-atom transfer from a series of p-substituted phenols to cubane Mn4O4L6 (L = O2PPh2) (1) reveals the activation energy to form the transition state is proportional to the phenolic O-H bond dissociation energy. New implications for water oxidation and charge recombination in photosystem II are described.
| Original language | English |
|---|---|
| Pages (from-to) | 11843-11847 |
| Number of pages | 5 |
| Journal | Physical Chemistry Chemical Physics |
| Volume | 16 |
| Issue number | 24 |
| DOIs | |
| Publication status | Published - Jun 28 2014 |
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ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Physics and Astronomy(all)
- Medicine(all)
Cite this
Entropy and enthalpy contributions to the kinetics of proton coupled electron transfer to the Mn4O4(O2PPh 2)6 cubane. / Carrell, Thomas G.; Smith, Paul F.; Dennes, Joseph; Dismukes, G Charles.
In: Physical Chemistry Chemical Physics, Vol. 16, No. 24, 28.06.2014, p. 11843-11847.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Entropy and enthalpy contributions to the kinetics of proton coupled electron transfer to the Mn4O4(O2PPh 2)6 cubane
AU - Carrell, Thomas G.
AU - Smith, Paul F.
AU - Dennes, Joseph
AU - Dismukes, G Charles
PY - 2014/6/28
Y1 - 2014/6/28
N2 - The dependence of rate, entropy of activation, and (1H/ 2H) kinetic isotope effect for H-atom transfer from a series of p-substituted phenols to cubane Mn4O4L6 (L = O2PPh2) (1) reveals the activation energy to form the transition state is proportional to the phenolic O-H bond dissociation energy. New implications for water oxidation and charge recombination in photosystem II are described.
AB - The dependence of rate, entropy of activation, and (1H/ 2H) kinetic isotope effect for H-atom transfer from a series of p-substituted phenols to cubane Mn4O4L6 (L = O2PPh2) (1) reveals the activation energy to form the transition state is proportional to the phenolic O-H bond dissociation energy. New implications for water oxidation and charge recombination in photosystem II are described.
UR - http://www.scopus.com/inward/record.url?scp=84901746119&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84901746119&partnerID=8YFLogxK
U2 - 10.1039/c3cp55200d
DO - 10.1039/c3cp55200d
M3 - Article
C2 - 24643330
AN - SCOPUS:84901746119
VL - 16
SP - 11843
EP - 11847
JO - Physical Chemistry Chemical Physics
JF - Physical Chemistry Chemical Physics
SN - 1463-9076
IS - 24
ER -