Et3NH+Co(CO)4-: Hydrogen-Bonded Adduct or Simple Ion Pair? Single-Crystal Neutron Diffraction Study at 15 K

Lee Brammer, Melinda C. McCann, R. Morris Bullock, Richard McMullen, Paul Sherwood

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88 Citations (Scopus)

Abstract

Et3NH+Co(CO)4- contains a short N–H…Co contact, which provides the closest approach between the anion and cation. Accurate structural characterization by neutron diffraction at 15 K shows the N–H…Co interaction to be linear with a long N–H bond length and a relatively short Co···H separation (Co···H = 2.613 (2)Å, N–H = 1.054 (1) Å, N–H···Co = 180.0°). This evidence is consistent with the presence of a three-center-four-electron hydrogen-bond-like N–H···Co interaction, though it does not rule out simple electrostatic attraction as the principal driving force behind association of the Et3NH+ and Co(CO)4- Ions.

Original languageEnglish
Pages (from-to)2339-2341
Number of pages3
JournalOrganometallics
Volume11
Issue number7
DOIs
Publication statusPublished - Jul 1 1992

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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