Eu3(AsS4)2 and AxEu 3-yAs5-zS10 (A = Li, Na): Compounds with simple and complex thioarsenate building blocks

Tarun K. Bera; Ratnasabapathy G. Iyer; Christos D. Malliakas; Mercouri G. Kanatzidis

doi:10.1021/ic701067r

Eu₃(AsS₄)₂ and A_xEu _3-yAs_5-zS₁₀ (A = Li, Na): Compounds with simple and complex thioarsenate building blocks

Tarun K. Bera, Ratnasabapathy G. Iyer, Christos D. Malliakas, Mercouri G. Kanatzidis

Northwestern University

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

Eu₃(AsS₄)₂ and A_xEu _3-yAs_5-zS₁₀ (A = Li, Na) are the members of a new thioarsenate family. They feature As⁵⁺ and As³⁺ centers, respectively. The rhombohedral Eu₃(AsS₄) ₂ features a new structure type consisting of eight-coordinate Eu²⁺ centers and AsS₄^3- anions, whereas the monoclinic A_xEu_3-yAs_5-zS₁₀ (Li _0.73Eu₃As_4.43S₁₀ and Na _0.66Eu_2.86As_4.54S₁₀) belong to the rathite sulfosalt family and are comprised of apparent [As₁₀S ₂₀]^10- segments linked with Eu²⁺ ions to give a three-dimensional network. They appear to be alkali-metal-stabilized derivatives of the putative parent phase "Eu₃-As ₅S₁₀".

Original language	English
Pages (from-to)	8466-8468
Number of pages	3
Journal	Inorganic Chemistry
Volume	46
Issue number	21
DOIs	https://doi.org/10.1021/ic701067r
Publication status	Published - Oct 15 2007

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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title = "Eu3(AsS4)2 and AxEu 3-yAs5-zS10 (A = Li, Na): Compounds with simple and complex thioarsenate building blocks",

abstract = "Eu3(AsS4)2 and AxEu 3-yAs5-zS10 (A = Li, Na) are the members of a new thioarsenate family. They feature As5+ and As3+ centers, respectively. The rhombohedral Eu3(AsS4) 2 features a new structure type consisting of eight-coordinate Eu2+ centers and AsS43- anions, whereas the monoclinic AxEu3-yAs5-zS10 (Li 0.73Eu3As4.43S10 and Na 0.66Eu2.86As4.54S10) belong to the rathite sulfosalt family and are comprised of apparent [As10S 20]10- segments linked with Eu2+ ions to give a three-dimensional network. They appear to be alkali-metal-stabilized derivatives of the putative parent phase {"}Eu3-As 5S10{"}.",

author = "Bera, {Tarun K.} and Iyer, {Ratnasabapathy G.} and Malliakas, {Christos D.} and Kanatzidis, {Mercouri G.}",

year = "2007",

month = oct,

day = "15",

doi = "10.1021/ic701067r",

language = "English",

volume = "46",

pages = "8466--8468",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "21",

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TY - JOUR

T1 - Eu3(AsS4)2 and AxEu 3-yAs5-zS10 (A = Li, Na)

T2 - Compounds with simple and complex thioarsenate building blocks

AU - Bera, Tarun K.

AU - Iyer, Ratnasabapathy G.

AU - Malliakas, Christos D.

AU - Kanatzidis, Mercouri G.

PY - 2007/10/15

Y1 - 2007/10/15

N2 - Eu3(AsS4)2 and AxEu 3-yAs5-zS10 (A = Li, Na) are the members of a new thioarsenate family. They feature As5+ and As3+ centers, respectively. The rhombohedral Eu3(AsS4) 2 features a new structure type consisting of eight-coordinate Eu2+ centers and AsS43- anions, whereas the monoclinic AxEu3-yAs5-zS10 (Li 0.73Eu3As4.43S10 and Na 0.66Eu2.86As4.54S10) belong to the rathite sulfosalt family and are comprised of apparent [As10S 20]10- segments linked with Eu2+ ions to give a three-dimensional network. They appear to be alkali-metal-stabilized derivatives of the putative parent phase "Eu3-As 5S10".

AB - Eu3(AsS4)2 and AxEu 3-yAs5-zS10 (A = Li, Na) are the members of a new thioarsenate family. They feature As5+ and As3+ centers, respectively. The rhombohedral Eu3(AsS4) 2 features a new structure type consisting of eight-coordinate Eu2+ centers and AsS43- anions, whereas the monoclinic AxEu3-yAs5-zS10 (Li 0.73Eu3As4.43S10 and Na 0.66Eu2.86As4.54S10) belong to the rathite sulfosalt family and are comprised of apparent [As10S 20]10- segments linked with Eu2+ ions to give a three-dimensional network. They appear to be alkali-metal-stabilized derivatives of the putative parent phase "Eu3-As 5S10".

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JO - Inorganic Chemistry

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Eu₃(AsS₄)₂ and A_xEu _3-yAs_5-zS₁₀ (A = Li, Na): Compounds with simple and complex thioarsenate building blocks

Abstract

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