Excitonic coupling in linear and trefoil trimer perylenediimide molecules probed by single-molecule spectroscopy

Hyejin Yoo, Shu Furumaki, Jaesung Yang, Ji Eun Lee, Heejae Chung, Tatsuya Oba, Hiroyuki Kobayashi, Boris Rybtchinski, Thea M. Wilson, Michael R Wasielewski, Martin Vacha, Dongho Kim

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

Perylenediimide (PDI) molecules are promising building blocks for photophysical studies of electronic interactions within multichromophore arrays. Such PDI arrays are important materials for fabrication of molecular nanodevices such as organic light-emitting diodes, organic semiconductors, and biosensors because of their high photostability, chemical and physical inertness, electron affinity, and high tinctorial strength over the entire visible spectrum. In this work, PDIs have been organized into linear (L3) and trefoil (T3) trimer molecules and investigated by single-molecule fluorescence microscopy to probe the relationship between molecular structures and interchromophoric electronic interactions. We found a broad distribution of coupling strengths in both L3 and T3 and hence strong/weak coupling between PDI units by monitoring spectral peak shifts in single-molecule fluorescence spectra upon sequential photobleaching of each constituent chromophore. In addition, we used a wide-field defocused imaging technique to resolve heterogeneities in molecular structures of L3 and T3 embedded in a PMMA polymer matrix. A systematic comparison between the two sets of experimental results allowed us to infer the correlation between intermolecular interactions and molecular structures. Our results show control of the PDI intermolecular interactions using suitable multichromophoric structures.

Original languageEnglish
Pages (from-to)12878-12886
Number of pages9
JournalJournal of Physical Chemistry B
Volume116
Issue number42
DOIs
Publication statusPublished - Oct 25 2012

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trimers
Spectroscopy
Molecular structure
Molecules
molecular structure
spectroscopy
molecules
interactions
Photobleaching
Electron affinity
fluorescence
Semiconducting organic compounds
Fluorescence microscopy
Organic light emitting diodes (OLED)
organic semiconductors
Polymethyl Methacrylate
Chromophores
high strength
visible spectrum
electron affinity

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Materials Chemistry
  • Surfaces, Coatings and Films

Cite this

Excitonic coupling in linear and trefoil trimer perylenediimide molecules probed by single-molecule spectroscopy. / Yoo, Hyejin; Furumaki, Shu; Yang, Jaesung; Lee, Ji Eun; Chung, Heejae; Oba, Tatsuya; Kobayashi, Hiroyuki; Rybtchinski, Boris; Wilson, Thea M.; Wasielewski, Michael R; Vacha, Martin; Kim, Dongho.

In: Journal of Physical Chemistry B, Vol. 116, No. 42, 25.10.2012, p. 12878-12886.

Research output: Contribution to journalArticle

Yoo, H, Furumaki, S, Yang, J, Lee, JE, Chung, H, Oba, T, Kobayashi, H, Rybtchinski, B, Wilson, TM, Wasielewski, MR, Vacha, M & Kim, D 2012, 'Excitonic coupling in linear and trefoil trimer perylenediimide molecules probed by single-molecule spectroscopy', Journal of Physical Chemistry B, vol. 116, no. 42, pp. 12878-12886. https://doi.org/10.1021/jp307394x
Yoo, Hyejin ; Furumaki, Shu ; Yang, Jaesung ; Lee, Ji Eun ; Chung, Heejae ; Oba, Tatsuya ; Kobayashi, Hiroyuki ; Rybtchinski, Boris ; Wilson, Thea M. ; Wasielewski, Michael R ; Vacha, Martin ; Kim, Dongho. / Excitonic coupling in linear and trefoil trimer perylenediimide molecules probed by single-molecule spectroscopy. In: Journal of Physical Chemistry B. 2012 ; Vol. 116, No. 42. pp. 12878-12886.
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