Abstract
[Pd(triphosphine)(Ch3CN)](BF4)2 complexes have been prepared with mesityl or trimethoxybenzene substituents on the central phosphorus atom of the triphosphine ligand. An X-ray diffraction study of [Pd(MesetpE is Bis((diethylphosphino)ethyl)mesitylphosphine has been completed. The cation has a square-planer structure with one methyl group of the central mesityl substituent blocking one potential coordination site. Kinetic studies of this complex in dimethylformamide indicate that the rate-determining step is the reaction of the [Pd-(MesetpE)(DMF)] cation with CO2.
| Original language | English |
|---|---|
| Pages (from-to) | 4835-4843 |
| Number of pages | 9 |
| Journal | Organometallics |
| Volume | 13 |
| Issue number | 12 |
| Publication status | Published - Dec 1994 |
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ASJC Scopus subject areas
- Inorganic Chemistry
- Organic Chemistry
Cite this
Exclusion of six-coordinate intermediates in the electrochemical reduction of CO2 catalyzed by [Pd(triphosphine)(CH3CN)](BF4)2 complexes. / Bernatis, P. R.; Miedaner, A.; Haltiwanger, C.; DuBois, Daniel L.
In: Organometallics, Vol. 13, No. 12, 12.1994, p. 4835-4843.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Exclusion of six-coordinate intermediates in the electrochemical reduction of CO2 catalyzed by [Pd(triphosphine)(CH3CN)](BF4)2 complexes
AU - Bernatis, P. R.
AU - Miedaner, A.
AU - Haltiwanger, C.
AU - DuBois, Daniel L
PY - 1994/12
Y1 - 1994/12
N2 - [Pd(triphosphine)(Ch3CN)](BF4)2 complexes have been prepared with mesityl or trimethoxybenzene substituents on the central phosphorus atom of the triphosphine ligand. An X-ray diffraction study of [Pd(MesetpE is Bis((diethylphosphino)ethyl)mesitylphosphine has been completed. The cation has a square-planer structure with one methyl group of the central mesityl substituent blocking one potential coordination site. Kinetic studies of this complex in dimethylformamide indicate that the rate-determining step is the reaction of the [Pd-(MesetpE)(DMF)] cation with CO2.
AB - [Pd(triphosphine)(Ch3CN)](BF4)2 complexes have been prepared with mesityl or trimethoxybenzene substituents on the central phosphorus atom of the triphosphine ligand. An X-ray diffraction study of [Pd(MesetpE is Bis((diethylphosphino)ethyl)mesitylphosphine has been completed. The cation has a square-planer structure with one methyl group of the central mesityl substituent blocking one potential coordination site. Kinetic studies of this complex in dimethylformamide indicate that the rate-determining step is the reaction of the [Pd-(MesetpE)(DMF)] cation with CO2.
UR - http://www.scopus.com/inward/record.url?scp=0028733299&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0028733299&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0028733299
VL - 13
SP - 4835
EP - 4843
JO - Organometallics
JF - Organometallics
SN - 0276-7333
IS - 12
ER -