Abstract
The authors report on the efforts to broaden the scope of the particular polymerization process using highly reactive, efficiently prepared methylenecyclopropane and organolanthanide catalysts of the type (Cp′2LnH)2 (Cp′ = η5-Me5C5; Ln = lanthanide), the activities of which can be significantly varied with the Ln3+ ionic radius. Results represent an attractive elaboration of the scope of exo-methylenecycloalkane ring-opening Ziegler polymerization. Both a more readily available and reactive monomer as well as tunable organo-f-element are shown to be compatible with such routes to exo-methylene-functionalized polyolefins.
| Original language | English |
|---|---|
| Pages (from-to) | 4625-4626 |
| Number of pages | 2 |
| Journal | Macromolecules |
| Volume | 27 |
| Issue number | 16 |
| Publication status | Published - Aug 1 1994 |
Fingerprint
ASJC Scopus subject areas
- Materials Chemistry
Cite this
exo-methylene-functionalized polyethylenes via ring-opening ziegler polymerization. Product control in organolanthanide-catalyzed methylenecyclopropane polymerization/copolymerization. / Yang, Xinmin; Seyam, Afif M.; Fu, Peng Fei; Marks, Tobin J.
In: Macromolecules, Vol. 27, No. 16, 01.08.1994, p. 4625-4626.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - exo-methylene-functionalized polyethylenes via ring-opening ziegler polymerization. Product control in organolanthanide-catalyzed methylenecyclopropane polymerization/copolymerization
AU - Yang, Xinmin
AU - Seyam, Afif M.
AU - Fu, Peng Fei
AU - Marks, Tobin J
PY - 1994/8/1
Y1 - 1994/8/1
N2 - The authors report on the efforts to broaden the scope of the particular polymerization process using highly reactive, efficiently prepared methylenecyclopropane and organolanthanide catalysts of the type (Cp′2LnH)2 (Cp′ = η5-Me5C5; Ln = lanthanide), the activities of which can be significantly varied with the Ln3+ ionic radius. Results represent an attractive elaboration of the scope of exo-methylenecycloalkane ring-opening Ziegler polymerization. Both a more readily available and reactive monomer as well as tunable organo-f-element are shown to be compatible with such routes to exo-methylene-functionalized polyolefins.
AB - The authors report on the efforts to broaden the scope of the particular polymerization process using highly reactive, efficiently prepared methylenecyclopropane and organolanthanide catalysts of the type (Cp′2LnH)2 (Cp′ = η5-Me5C5; Ln = lanthanide), the activities of which can be significantly varied with the Ln3+ ionic radius. Results represent an attractive elaboration of the scope of exo-methylenecycloalkane ring-opening Ziegler polymerization. Both a more readily available and reactive monomer as well as tunable organo-f-element are shown to be compatible with such routes to exo-methylene-functionalized polyolefins.
UR - http://www.scopus.com/inward/record.url?scp=0028483607&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0028483607&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0028483607
VL - 27
SP - 4625
EP - 4626
JO - Macromolecules
JF - Macromolecules
SN - 0024-9297
IS - 16
ER -