Exploring the intermediates of photochemical CO2 reduction: Reaction of Re(dmb)(CO)3 COOH with CO2

Jay Agarwal, Henry F. Schaefer, Etsuko Fujita, Todd C. Harrop, James T. Muckerman

Research output: Contribution to journalArticlepeer-review

30 Citations (Scopus)


We have investigated the reaction of Re(dmb)(CO)3COOH with CO2 using density functional theory, and propose a mechanism for the production of CO. This mechanism supports the role of Re(dmb)(CO)3COOH as a key intermediate in the formation of CO. Our new experimental work supports the proposed scheme.

Original languageEnglish
Pages (from-to)6797-6799
Number of pages3
JournalChemical Communications
Issue number54
Publication statusPublished - Jun 12 2012

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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