Fabrication and use of nanometer-sized electrodes in electrochemistry

Reginald M. Penner; Michael J. Heben; Teresa L. Longin; Nathan S. Lewis

doi:10.1126/science.250.4984.1118

Fabrication and use of nanometer-sized electrodes in electrochemistry

Reginald M. Penner, Michael J. Heben, Teresa L. Longin, Nathan S. Lewis

California Institute of Technology

Research output: Contribution to journal › Article › peer-review

314 Citations (Scopus)

Abstract

Electrodes with electrochemical dimensions as small as 10 angstroms have been fabricated and used for electrochemical studies. These nanometer-scale electrodes have enabled the measurement of electron-transfer rate constants, k_het, that are two orders of magnitude faster than k_het values accessible with any other electrochemical method.

Original language	English
Pages (from-to)	1118-1121
Number of pages	4
Journal	Science
Volume	250
Issue number	494
DOIs	https://doi.org/10.1126/science.250.4984.1118
Publication status	Published - 1990

ASJC Scopus subject areas

General

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title = "Fabrication and use of nanometer-sized electrodes in electrochemistry",

abstract = "Electrodes with electrochemical dimensions as small as 10 angstroms have been fabricated and used for electrochemical studies. These nanometer-scale electrodes have enabled the measurement of electron-transfer rate constants, khet, that are two orders of magnitude faster than khet values accessible with any other electrochemical method.",

author = "Penner, {Reginald M.} and Heben, {Michael J.} and Longin, {Teresa L.} and Lewis, {Nathan S.}",

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AB - Electrodes with electrochemical dimensions as small as 10 angstroms have been fabricated and used for electrochemical studies. These nanometer-scale electrodes have enabled the measurement of electron-transfer rate constants, khet, that are two orders of magnitude faster than khet values accessible with any other electrochemical method.

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