fac-Tricarbonylchlorobis(pyridine-N)-rhenium and fac-Tricarbonylchlorobis(4,4′-bipyridine-N)rhenium

Suzanne Bélanger, Joseph T. Hupp, Charlotte L. Stern

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Abstract

Structural analyses for the title compounds, (OC-6-32)-tricarbonylchlorobis(pyridine-N)rhenium(I), [ReCl-(C5H5N)2(CO)3], and (OC-6-32)-tricarbonylchlorobis-(4,4′-bipyridine-N)rhenium(I), [ReCl(C10H8N2)2(CO)3], show that both complexes have the expected facoctahedral geometry. The bipyridine complex has local C2 symmetry, with the rotation axis bisecting the N - Re - N′ and OC - Re - CO angles. In contrast with closely related tetrameric assemblies which crystallize as porous channel-containing structures, the title compounds form dense crystals which are packed in a herring-bone fashion.

Original languageEnglish
Pages (from-to)1596-1600
Number of pages5
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume54
Issue number11
DOIs
Publication statusPublished - Nov 15 1998

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ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)

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