Facile conversion of alcohols into esters and dihydrogen catalyzed by new ruthenium complexes

Jing Zhang; Gregory Leitus; Yehoshoa Ben-David; David Milstein

doi:10.1021/ja052862b

Facile conversion of alcohols into esters and dihydrogen catalyzed by new ruthenium complexes

Jing Zhang, Gregory Leitus, Yehoshoa Ben-David, David Milstein

Weizmann Institute of Science, Israel

Research output: Contribution to journal › Article › peer-review

539 Citations (Scopus)

Abstract

An efficient, environmentally benign method for the preparation of esters from alcohols under mild, neutral conditions without the need for carboxylic acid derivatives and condensing agents was developed. Catalyst design, based on new Ru(II) hydrido carbonyl complexes incorporating electron-rich PNP and PNN ligands has resulted in the novel complex (I) which is an outstanding catalyst for the dehydrogenation of primary alcohols to esters and H₂ under neutral conditions.

Original language	English
Pages (from-to)	10840-10841
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	127
Issue number	31
DOIs	https://doi.org/10.1021/ja052862b
Publication status	Published - Aug 10 2005

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

Access to Document

10.1021/ja052862b

Fingerprint Dive into the research topics of 'Facile conversion of alcohols into esters and dihydrogen catalyzed by new ruthenium complexes'. Together they form a unique fingerprint.

Cite this

@article{4f33b89115ee45af8eccca4f08d99aa8,

title = "Facile conversion of alcohols into esters and dihydrogen catalyzed by new ruthenium complexes",

abstract = "An efficient, environmentally benign method for the preparation of esters from alcohols under mild, neutral conditions without the need for carboxylic acid derivatives and condensing agents was developed. Catalyst design, based on new Ru(II) hydrido carbonyl complexes incorporating electron-rich PNP and PNN ligands has resulted in the novel complex (I) which is an outstanding catalyst for the dehydrogenation of primary alcohols to esters and H2 under neutral conditions.",

author = "Jing Zhang and Gregory Leitus and Yehoshoa Ben-David and David Milstein",

year = "2005",

month = aug,

day = "10",

doi = "10.1021/ja052862b",

language = "English",

volume = "127",

pages = "10840--10841",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "31",

}

TY - JOUR

T1 - Facile conversion of alcohols into esters and dihydrogen catalyzed by new ruthenium complexes

AU - Zhang, Jing

AU - Leitus, Gregory

AU - Ben-David, Yehoshoa

AU - Milstein, David

PY - 2005/8/10

Y1 - 2005/8/10

N2 - An efficient, environmentally benign method for the preparation of esters from alcohols under mild, neutral conditions without the need for carboxylic acid derivatives and condensing agents was developed. Catalyst design, based on new Ru(II) hydrido carbonyl complexes incorporating electron-rich PNP and PNN ligands has resulted in the novel complex (I) which is an outstanding catalyst for the dehydrogenation of primary alcohols to esters and H2 under neutral conditions.

AB - An efficient, environmentally benign method for the preparation of esters from alcohols under mild, neutral conditions without the need for carboxylic acid derivatives and condensing agents was developed. Catalyst design, based on new Ru(II) hydrido carbonyl complexes incorporating electron-rich PNP and PNN ligands has resulted in the novel complex (I) which is an outstanding catalyst for the dehydrogenation of primary alcohols to esters and H2 under neutral conditions.

UR - http://www.scopus.com/inward/record.url?scp=23744449879&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=23744449879&partnerID=8YFLogxK

U2 - 10.1021/ja052862b

DO - 10.1021/ja052862b

M3 - Article

C2 - 16076184

AN - SCOPUS:23744449879

VL - 127

SP - 10840

EP - 10841

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 31

ER -

Facile conversion of alcohols into esters and dihydrogen catalyzed by new ruthenium complexes

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Cite this