Facile conversion of alcohols into esters and dihydrogen catalyzed by new ruthenium complexes

Jing Zhang; Gregory Leitus; Yehoshoa Ben-David; David Milstein

doi:10.1021/ja052862b

Facile conversion of alcohols into esters and dihydrogen catalyzed by new ruthenium complexes

Jing Zhang, Gregory Leitus, Yehoshoa Ben-David, David Milstein

Weizmann Institute of Science, Israel

Research output: Contribution to journal › Article

503 Citations (Scopus)

Abstract

An efficient, environmentally benign method for the preparation of esters from alcohols under mild, neutral conditions without the need for carboxylic acid derivatives and condensing agents was developed. Catalyst design, based on new Ru(II) hydrido carbonyl complexes incorporating electron-rich PNP and PNN ligands has resulted in the novel complex (I) which is an outstanding catalyst for the dehydrogenation of primary alcohols to esters and H₂ under neutral conditions.

Original language	English
Pages (from-to)	10840-10841
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	127
Issue number	31
DOIs	https://doi.org/10.1021/ja052862b
Publication status	Published - Aug 10 2005

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Ruthenium

Esters

Alcohols

Catalysts

Dehydrogenation

Carboxylic Acids

Carboxylic acids

Ligands

Electrons

Derivatives

ASJC Scopus subject areas

Chemistry(all)

Cite this

Zhang, J., Leitus, G., Ben-David, Y., & Milstein, D. (2005). Facile conversion of alcohols into esters and dihydrogen catalyzed by new ruthenium complexes. Journal of the American Chemical Society, 127(31), 10840-10841. https://doi.org/10.1021/ja052862b

Facile conversion of alcohols into esters and dihydrogen catalyzed by new ruthenium complexes. / Zhang, Jing; Leitus, Gregory; Ben-David, Yehoshoa; Milstein, David.

In: Journal of the American Chemical Society, Vol. 127, No. 31, 10.08.2005, p. 10840-10841.

Research output: Contribution to journal › Article

Zhang, J, Leitus, G, Ben-David, Y & Milstein, D 2005, 'Facile conversion of alcohols into esters and dihydrogen catalyzed by new ruthenium complexes', Journal of the American Chemical Society, vol. 127, no. 31, pp. 10840-10841. https://doi.org/10.1021/ja052862b

Zhang J, Leitus G, Ben-David Y, Milstein D. Facile conversion of alcohols into esters and dihydrogen catalyzed by new ruthenium complexes. Journal of the American Chemical Society. 2005 Aug 10;127(31):10840-10841. https://doi.org/10.1021/ja052862b

Zhang, Jing ; Leitus, Gregory ; Ben-David, Yehoshoa ; Milstein, David. / Facile conversion of alcohols into esters and dihydrogen catalyzed by new ruthenium complexes. In: Journal of the American Chemical Society. 2005 ; Vol. 127, No. 31. pp. 10840-10841.

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10.1021/ja052862b