Finding the perfect match

Halogen vs hydrogen bonding

Tanya Shirman, Meital Boterashvili, Meital Orbach, Dalia Freeman, Linda J W Shimon, Michal Lahav, Milko van der Boom

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

The prediction of supramolecular structures involving different weak interactions is challenging. In this study, single-atom modifications to the molecular structure allow us to address their hierarchy. The resulting series of unimolecular assemblies are mainly based on halogen bonding (XB), hydrogen bonding (HB), or a combination of both. By varying the XB donor (F, Cl, Br, and I) and the XB and HB acceptors (pyridine vs pyridine-N-oxide) we can control the primary motifs directing the structure.

Original languageEnglish
Pages (from-to)4756-4759
Number of pages4
JournalCrystal Growth and Design
Volume15
Issue number10
DOIs
Publication statusPublished - Oct 7 2015

Fingerprint

Halogens
Pyridine
halogens
Hydrogen bonds
pyridines
hydrogen
Molecular structure
Atoms
assemblies
hierarchies
Oxides
molecular structure
oxides
predictions
atoms
pyridine N-oxide
pyridine

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Shirman, T., Boterashvili, M., Orbach, M., Freeman, D., Shimon, L. J. W., Lahav, M., & van der Boom, M. (2015). Finding the perfect match: Halogen vs hydrogen bonding. Crystal Growth and Design, 15(10), 4756-4759. https://doi.org/10.1021/acs.cgd.5b01260

Finding the perfect match : Halogen vs hydrogen bonding. / Shirman, Tanya; Boterashvili, Meital; Orbach, Meital; Freeman, Dalia; Shimon, Linda J W; Lahav, Michal; van der Boom, Milko.

In: Crystal Growth and Design, Vol. 15, No. 10, 07.10.2015, p. 4756-4759.

Research output: Contribution to journalArticle

Shirman, T, Boterashvili, M, Orbach, M, Freeman, D, Shimon, LJW, Lahav, M & van der Boom, M 2015, 'Finding the perfect match: Halogen vs hydrogen bonding', Crystal Growth and Design, vol. 15, no. 10, pp. 4756-4759. https://doi.org/10.1021/acs.cgd.5b01260
Shirman T, Boterashvili M, Orbach M, Freeman D, Shimon LJW, Lahav M et al. Finding the perfect match: Halogen vs hydrogen bonding. Crystal Growth and Design. 2015 Oct 7;15(10):4756-4759. https://doi.org/10.1021/acs.cgd.5b01260
Shirman, Tanya ; Boterashvili, Meital ; Orbach, Meital ; Freeman, Dalia ; Shimon, Linda J W ; Lahav, Michal ; van der Boom, Milko. / Finding the perfect match : Halogen vs hydrogen bonding. In: Crystal Growth and Design. 2015 ; Vol. 15, No. 10. pp. 4756-4759.
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