Fluorine Tuning of Morphology, Energy Loss, and Carrier Dynamics in Perylenediimide Polymer Solar Cells

Weigang Zhu, Joaquin M. Alzola, Thomas J. Aldrich, Kevin L. Kohlstedt, Ding Zheng, Patrick E. Hartnett, Nicholas D. Eastham, Wei Huang, Gang Wang, Ryan M. Young, George C. Schatz, Michael R. Wasielewski, Antonio Facchetti, Ferdinand S. Melkonyan, Tobin J. Marks

Research output: Contribution to journalArticle

Abstract

We investigate backbone fluorination effects in bulk-heterojunction (BHJ) polymer solar cells (PSCs) with the fluorine-poor PBDTT-FTTE and fluorine-rich PBDTTF-FTTE donor polymers, paired with the perylenediimide (PDI) 3D "propeller acceptor" Ph(PDI)3. The PBDTTF-FTTE:Ph(PDI)3 devices exhibit a >50% power conversion efficiency (PCE, up to 9.1%) increase versus PBDTT-FTTE:Ph(PDI)3. This enhancement reflects structurally optimized phase separation due to templating effects, affording reduced energy loss, higher electron mobility, greater free charge lifetimes and yields, and lower bimolecular recombination, as quantified by UPS, AFM, TEM, GIWAXS, SCLC, light intensity dependence measurements, and fs/ns transient absorption (TA) spectroscopy. In PBDTTF-FTTE, the DFT-computed dipole orientations of the ground and excitonic states are nearly antiparallel, explaining the longer free charge lifetimes, minimized recombination, and lowered exciton binding energy. The PBDTTF-FTTE:Ph(PDI)3 performance enhancement vs that of the fluorine-poor PBDTT-FTTE:Ph(PDI)3 analogue as well as the overall PSC performance exceeds that of the corresponding PC71BM- and ITIC-Th-based cells.

Original languageEnglish
Pages (from-to)2695-2702
Number of pages8
JournalACS Energy Letters
DOIs
Publication statusAccepted/In press - Jan 1 2019

Fingerprint

Fluorine
Energy dissipation
Tuning
Fluorination
Electron mobility
Propellers
Binding energy
Absorption spectroscopy
Discrete Fourier transforms
Excitons
Phase separation
Conversion efficiency
Heterojunctions
Transmission electron microscopy
Polymers
Polymer solar cells
perylenediimide

ASJC Scopus subject areas

  • Chemistry (miscellaneous)
  • Renewable Energy, Sustainability and the Environment
  • Fuel Technology
  • Energy Engineering and Power Technology
  • Materials Chemistry

Cite this

Fluorine Tuning of Morphology, Energy Loss, and Carrier Dynamics in Perylenediimide Polymer Solar Cells. / Zhu, Weigang; Alzola, Joaquin M.; Aldrich, Thomas J.; Kohlstedt, Kevin L.; Zheng, Ding; Hartnett, Patrick E.; Eastham, Nicholas D.; Huang, Wei; Wang, Gang; Young, Ryan M.; Schatz, George C.; Wasielewski, Michael R.; Facchetti, Antonio; Melkonyan, Ferdinand S.; Marks, Tobin J.

In: ACS Energy Letters, 01.01.2019, p. 2695-2702.

Research output: Contribution to journalArticle

Zhu, W, Alzola, JM, Aldrich, TJ, Kohlstedt, KL, Zheng, D, Hartnett, PE, Eastham, ND, Huang, W, Wang, G, Young, RM, Schatz, GC, Wasielewski, MR, Facchetti, A, Melkonyan, FS & Marks, TJ 2019, 'Fluorine Tuning of Morphology, Energy Loss, and Carrier Dynamics in Perylenediimide Polymer Solar Cells', ACS Energy Letters, pp. 2695-2702. https://doi.org/10.1021/acsenergylett.9b02146
Zhu, Weigang ; Alzola, Joaquin M. ; Aldrich, Thomas J. ; Kohlstedt, Kevin L. ; Zheng, Ding ; Hartnett, Patrick E. ; Eastham, Nicholas D. ; Huang, Wei ; Wang, Gang ; Young, Ryan M. ; Schatz, George C. ; Wasielewski, Michael R. ; Facchetti, Antonio ; Melkonyan, Ferdinand S. ; Marks, Tobin J. / Fluorine Tuning of Morphology, Energy Loss, and Carrier Dynamics in Perylenediimide Polymer Solar Cells. In: ACS Energy Letters. 2019 ; pp. 2695-2702.
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