Formal loss of an H radical by a cobalt complex via metal-ligand cooperation

Eugene Khaskin, Yael Diskin-Posner, Lev Weiner, Gregory Leitus, David Milstein

Research output: Contribution to journalArticle

42 Citations (Scopus)

Abstract

A (PNP)Co(i)methyl diamagnetic complex formally loses an H atom from the pincer ligand, exhibiting a long-range metal-ligand cooperation in what may be considered as an unusual example of 'C-H cleavage'. Spectroscopic data indicate that the product is a neutral Co(i) complex with a radical delocalized in the ligand backbone.

Original languageEnglish
Pages (from-to)2771-2773
Number of pages3
JournalChemical Communications
Volume49
Issue number27
DOIs
Publication statusPublished - Apr 7 2013

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Cobalt
Metals
Ligands
Atoms

ASJC Scopus subject areas

  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Catalysis
  • Chemistry(all)

Cite this

Formal loss of an H radical by a cobalt complex via metal-ligand cooperation. / Khaskin, Eugene; Diskin-Posner, Yael; Weiner, Lev; Leitus, Gregory; Milstein, David.

In: Chemical Communications, Vol. 49, No. 27, 07.04.2013, p. 2771-2773.

Research output: Contribution to journalArticle

Khaskin, Eugene ; Diskin-Posner, Yael ; Weiner, Lev ; Leitus, Gregory ; Milstein, David. / Formal loss of an H radical by a cobalt complex via metal-ligand cooperation. In: Chemical Communications. 2013 ; Vol. 49, No. 27. pp. 2771-2773.
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