Abstract
A (PNP)Co(i)methyl diamagnetic complex formally loses an H atom from the pincer ligand, exhibiting a long-range metal–ligand cooperation in what may be considered as an unusual example of “C–H cleavage”. Spectroscopic data indicate that the product is a neutral Co(i) complex with a radical delocalized in the ligand backbone.
| Original language | English |
|---|---|
| Pages (from-to) | 2771-2773 |
| Number of pages | 3 |
| Journal | Chemical Communications |
| Volume | 49 |
| Issue number | 27 |
| DOIs | |
| Publication status | Published - Mar 7 2013 |
ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry
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Khaskin, E., Diskin-Posner, Y., Weiner, L., Leitus, G., & Milstein, D. (2013). Formal loss of an H radical by a cobalt complex via metal–ligand cooperation. Chemical Communications, 49(27), 2771-2773. https://doi.org/10.1039/c3cc39049g