Formation of a high valent di-μ-oxo manganese dimer in aqueous solution

Rajesh Manchanda, Gary W Brudvig, Robert H. Crabtree, Joseph E. Sarneski, Mary Didiuk

Research output: Contribution to journalArticle

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Abstract

We find an unusual example in which different clusters can be isolated from the same reaction mixture depending on the choice of counter-ion. The complex [(bipy)2Mn(III)(μ-O)2Mn(IV)(bipy)2]3+ (1) (bipy=2,2′-dipyridyl) is isolated from Mn(II) and permanganate in acetate buffer with ClO4 -, but [(bipy)(H2O)Mn(III)(μ-O)(μ-OAc)2Mn(III)(bipy)(H2O)]2+ (2) with NO3 -. 1e-/2H+ or 1e-/1H+ proton-coupled electron transfer chemistry is found for 2 according to the type of buffer used. The new complex [(bipy)(H2O)Mn(III)(μ-O)2(μ-OAc)Mn(IV)(bipy)(H2O)]2+ (3) is also postulated as an intermediate in the formation of 1.

Original languageEnglish
Pages (from-to)135-137
Number of pages3
JournalInorganica Chimica Acta
Volume212
Issue number1-2
DOIs
Publication statusPublished - 1993

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Radiation counters
Manganese
Dimers
manganese
Buffers
Protons
buffers
dimers
aqueous solutions
Electrons
acetates
electron transfer
counters
Acetates
Ions
chemistry
protons
ions
perchlorate
permanganic acid

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

Formation of a high valent di-μ-oxo manganese dimer in aqueous solution. / Manchanda, Rajesh; Brudvig, Gary W; Crabtree, Robert H.; Sarneski, Joseph E.; Didiuk, Mary.

In: Inorganica Chimica Acta, Vol. 212, No. 1-2, 1993, p. 135-137.

Research output: Contribution to journalArticle

Manchanda, Rajesh ; Brudvig, Gary W ; Crabtree, Robert H. ; Sarneski, Joseph E. ; Didiuk, Mary. / Formation of a high valent di-μ-oxo manganese dimer in aqueous solution. In: Inorganica Chimica Acta. 1993 ; Vol. 212, No. 1-2. pp. 135-137.
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N2 - We find an unusual example in which different clusters can be isolated from the same reaction mixture depending on the choice of counter-ion. The complex [(bipy)2Mn(III)(μ-O)2Mn(IV)(bipy)2]3+ (1) (bipy=2,2′-dipyridyl) is isolated from Mn(II) and permanganate in acetate buffer with ClO4 -, but [(bipy)(H2O)Mn(III)(μ-O)(μ-OAc)2Mn(III)(bipy)(H2O)]2+ (2) with NO3 -. 1e-/2H+ or 1e-/1H+ proton-coupled electron transfer chemistry is found for 2 according to the type of buffer used. The new complex [(bipy)(H2O)Mn(III)(μ-O)2(μ-OAc)Mn(IV)(bipy)(H2O)]2+ (3) is also postulated as an intermediate in the formation of 1.

AB - We find an unusual example in which different clusters can be isolated from the same reaction mixture depending on the choice of counter-ion. The complex [(bipy)2Mn(III)(μ-O)2Mn(IV)(bipy)2]3+ (1) (bipy=2,2′-dipyridyl) is isolated from Mn(II) and permanganate in acetate buffer with ClO4 -, but [(bipy)(H2O)Mn(III)(μ-O)(μ-OAc)2Mn(III)(bipy)(H2O)]2+ (2) with NO3 -. 1e-/2H+ or 1e-/1H+ proton-coupled electron transfer chemistry is found for 2 according to the type of buffer used. The new complex [(bipy)(H2O)Mn(III)(μ-O)2(μ-OAc)Mn(IV)(bipy)(H2O)]2+ (3) is also postulated as an intermediate in the formation of 1.

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