Abstract
A predictive model for the formation of new acid sites in a dilute solid solution of two component oxides is being developed by examining the electrostatic potential at the substituting cation site and the changes in the matrix necessary to balance the stoichiometry. When the prediction was used to compare with experimental results, the satisfactory comparison suggests that the electrostatic potential and the balance of stoichiometry are the two dominant factors in new acid site formation. The implications of this are discussed.
| Original language | English |
|---|---|
| Pages (from-to) | 191-196 |
| Number of pages | 6 |
| Journal | Journal of Solid State Chemistry |
| Volume | 52 |
| Issue number | 2 |
| DOIs | |
| Publication status | Published - 1984 |
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ASJC Scopus subject areas
- Inorganic Chemistry
- Physical and Theoretical Chemistry
- Materials Chemistry
Cite this
Formation of new acid sites in dilute oxide solid solutions : A predictive model. / Kung, Harold H.
In: Journal of Solid State Chemistry, Vol. 52, No. 2, 1984, p. 191-196.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Formation of new acid sites in dilute oxide solid solutions
T2 - A predictive model
AU - Kung, Harold H
PY - 1984
Y1 - 1984
N2 - A predictive model for the formation of new acid sites in a dilute solid solution of two component oxides is being developed by examining the electrostatic potential at the substituting cation site and the changes in the matrix necessary to balance the stoichiometry. When the prediction was used to compare with experimental results, the satisfactory comparison suggests that the electrostatic potential and the balance of stoichiometry are the two dominant factors in new acid site formation. The implications of this are discussed.
AB - A predictive model for the formation of new acid sites in a dilute solid solution of two component oxides is being developed by examining the electrostatic potential at the substituting cation site and the changes in the matrix necessary to balance the stoichiometry. When the prediction was used to compare with experimental results, the satisfactory comparison suggests that the electrostatic potential and the balance of stoichiometry are the two dominant factors in new acid site formation. The implications of this are discussed.
UR - http://www.scopus.com/inward/record.url?scp=0021410835&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0021410835&partnerID=8YFLogxK
U2 - 10.1016/0022-4596(84)90191-9
DO - 10.1016/0022-4596(84)90191-9
M3 - Article
AN - SCOPUS:0021410835
VL - 52
SP - 191
EP - 196
JO - Journal of Solid State Chemistry
JF - Journal of Solid State Chemistry
SN - 0022-4596
IS - 2
ER -