Formation of persulphate from sodium sulphite and molecular oxygen catalysed by H5PV2Mo10O40-aerobic epoxidation and hydrolysis

Amir Rubinstein, Raanan Carmeli, Ronny Neumann

Research output: Contribution to journal › Article

7 Citations (Scopus)

Abstract

The H5PV2Mo10O40 polyoxometalate catalysed the electron transfer oxidation of sulphite to yield a sulphite radical, SO3- that upon addition of O2 yielded a peroxosulphate species efficient for the H5PV2Mo10O40 catalysed epoxidation of alkenes. The acidic polyoxometalate further catalysed hydrolysis of the epoxide to give vicinal diols in high yields. This journal is

Original languageEnglish
Pages (from-to)13247-13249
Number of pages3
JournalChemical Communications
Volume50
Issue number87
DOIs
Publication statusPublished - Nov 11 2014

Fingerprint

Sulfites
Epoxidation
Molecular oxygen
Olefins
Hydrolysis
Sodium
Oxidation
Electrons
Epoxy Compounds
Alkenes
sodium sulfite
polyoxometalate I

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Ceramics and Composites
  • Electronic, Optical and Magnetic Materials
  • Surfaces, Coatings and Films
  • Materials Chemistry
  • Metals and Alloys

Cite this

Formation of persulphate from sodium sulphite and molecular oxygen catalysed by H5PV2Mo10O40-aerobic epoxidation and hydrolysis. / Rubinstein, Amir; Carmeli, Raanan; Neumann, Ronny.

In: Chemical Communications, Vol. 50, No. 87, 11.11.2014, p. 13247-13249.

Research output: Contribution to journal › Article

Rubinstein, A, Carmeli, R & Neumann, R 2014, 'Formation of persulphate from sodium sulphite and molecular oxygen catalysed by H5PV2Mo10O40-aerobic epoxidation and hydrolysis', Chemical Communications, vol. 50, no. 87, pp. 13247-13249. https://doi.org/10.1039/c4cc06304j
Rubinstein A, Carmeli R, Neumann R. Formation of persulphate from sodium sulphite and molecular oxygen catalysed by H5PV2Mo10O40-aerobic epoxidation and hydrolysis. Chemical Communications. 2014 Nov 11;50(87):13247-13249. https://doi.org/10.1039/c4cc06304j
Rubinstein, Amir ; Carmeli, Raanan ; Neumann, Ronny. / Formation of persulphate from sodium sulphite and molecular oxygen catalysed by H5PV2Mo10O40-aerobic epoxidation and hydrolysis. In: Chemical Communications. 2014 ; Vol. 50, No. 87. pp. 13247-13249.
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