Abstract
The H5PV2Mo10O40 polyoxometalate catalysed the electron transfer oxidation of sulphite to yield a sulphite radical, SO3- that upon addition of O2 yielded a peroxosulphate species efficient for the H5PV2Mo10O40 catalysed epoxidation of alkenes. The acidic polyoxometalate further catalysed hydrolysis of the epoxide to give vicinal diols in high yields. This journal is
| Original language | English |
|---|---|
| Pages (from-to) | 13247-13249 |
| Number of pages | 3 |
| Journal | Chemical Communications |
| Volume | 50 |
| Issue number | 87 |
| DOIs | |
| Publication status | Published - Nov 11 2014 |
ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry
Fingerprint Dive into the research topics of 'Formation of persulphate from sodium sulphite and molecular oxygen catalysed by H<sub>5</sub>PV<sub>2</sub>Mo<sub>10</sub>O<sub>40</sub>-aerobic epoxidation and hydrolysis'. Together they form a unique fingerprint.
Cite this
Rubinstein, A., Carmeli, R., & Neumann, R. (2014). Formation of persulphate from sodium sulphite and molecular oxygen catalysed by H5PV2Mo10O40-aerobic epoxidation and hydrolysis. Chemical Communications, 50(87), 13247-13249. https://doi.org/10.1039/c4cc06304j