Formation of persulphate from sodium sulphite and molecular oxygen catalysed by H5PV2Mo10O40-aerobic epoxidation and hydrolysis

Amir Rubinstein, Raanan Carmeli, Ronny Neumann

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

The H5PV2Mo10O40 polyoxometalate catalysed the electron transfer oxidation of sulphite to yield a sulphite radical, SO3- that upon addition of O2 yielded a peroxosulphate species efficient for the H5PV2Mo10O40 catalysed epoxidation of alkenes. The acidic polyoxometalate further catalysed hydrolysis of the epoxide to give vicinal diols in high yields. This journal is

Original languageEnglish
Pages (from-to)13247-13249
Number of pages3
JournalChemical Communications
Volume50
Issue number87
DOIs
Publication statusPublished - Nov 11 2014

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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