Abstract
A new reaction of haloalkylzinc compounds, leading to transition metal carbenes, is described; halomethylzinc and halobenzylzinc compounds react with ruthenium and iridium complexes to form methylene and benzylidene complexes, including the Grubbs catalyst.
| Original language | English |
|---|---|
| Pages (from-to) | 3189-3191 |
| Number of pages | 3 |
| Journal | Chemical Communications |
| Issue number | 30 |
| DOIs | |
| Publication status | Published - Aug 3 2007 |
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ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry
Cite this
Poverenov, E., & Milstein, D. (2007). Formation of transition metal carbenes using haloalkylzinc reagents. Chemical Communications, (30), 3189-3191. https://doi.org/10.1039/b705459a