From 1D chain to 3D network

A new family of inorganic-organic hybrid semiconductors MO3(L)x (M = Mo, W; L = organic linker) built on perovskite-like structure modules

Xiao Zhang, Mehdi Hejazi, Suraj J. Thiagarajan, William R. Woerner, Debasis Banerjee, Thomas J. Emge, Wenqian Xu, Simon J. Teat, Qihan Gong, Ahmad Safari, Ronggui Yang, John B. Parise, Jing Li

Research output: Contribution to journalArticle

31 Citations (Scopus)

Abstract

MO3 (M = Mo, W) or VI-VI binary compounds are important semiconducting oxides that show great promise for a variety of applications. In an effort to tune and enhance their properties in a systematic manner we have applied a designing strategy to deliberately introduce organic linker molecules in these perovskite-like crystal lattices. This approach has led to a wealth of new hybrid structures built on one-dimensional (1D) and two-dimensional (2D) VI-VI modules. The hybrid semiconductors exhibit a number of greatly improved properties and new functionality, including broad band gap tunability, negative thermal expansion, largely reduced thermal conductivity, and significantly enhanced dielectric constant compared to their MO3 parent phases.

Original languageEnglish
Pages (from-to)17401-17407
Number of pages7
JournalJournal of the American Chemical Society
Volume135
Issue number46
DOIs
Publication statusPublished - Nov 20 2013

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Thermal Conductivity
Semiconductors
Crystal lattices
Perovskite
Oxides
Thermal conductivity
Energy gap
Permittivity
Hot Temperature
Semiconductor materials
Molecules
Negative thermal expansion
perovskite

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

From 1D chain to 3D network : A new family of inorganic-organic hybrid semiconductors MO3(L)x (M = Mo, W; L = organic linker) built on perovskite-like structure modules. / Zhang, Xiao; Hejazi, Mehdi; Thiagarajan, Suraj J.; Woerner, William R.; Banerjee, Debasis; Emge, Thomas J.; Xu, Wenqian; Teat, Simon J.; Gong, Qihan; Safari, Ahmad; Yang, Ronggui; Parise, John B.; Li, Jing.

In: Journal of the American Chemical Society, Vol. 135, No. 46, 20.11.2013, p. 17401-17407.

Research output: Contribution to journalArticle

Zhang, X, Hejazi, M, Thiagarajan, SJ, Woerner, WR, Banerjee, D, Emge, TJ, Xu, W, Teat, SJ, Gong, Q, Safari, A, Yang, R, Parise, JB & Li, J 2013, 'From 1D chain to 3D network: A new family of inorganic-organic hybrid semiconductors MO3(L)x (M = Mo, W; L = organic linker) built on perovskite-like structure modules', Journal of the American Chemical Society, vol. 135, no. 46, pp. 17401-17407. https://doi.org/10.1021/ja4077556
Zhang, Xiao ; Hejazi, Mehdi ; Thiagarajan, Suraj J. ; Woerner, William R. ; Banerjee, Debasis ; Emge, Thomas J. ; Xu, Wenqian ; Teat, Simon J. ; Gong, Qihan ; Safari, Ahmad ; Yang, Ronggui ; Parise, John B. ; Li, Jing. / From 1D chain to 3D network : A new family of inorganic-organic hybrid semiconductors MO3(L)x (M = Mo, W; L = organic linker) built on perovskite-like structure modules. In: Journal of the American Chemical Society. 2013 ; Vol. 135, No. 46. pp. 17401-17407.
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