From 2-methylimidazole to 1,2,3-triazole: a topological transformation of ZIF-8 and ZIF-67 by post-synthetic modification

Mustafa Erkartal, Ufuk Erkilic, Benjamin Tam, Hakan Usta, Ozgur Yazaydin, Joseph T Hupp, Omar K. Farha, Unal Sen

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

Bridging ligand replacement in zeolitic imidazolate frameworks, ZIF-8 and ZIF-67, by 1,2,3-triazole was investigated. A complete substitution of 2-methylimidazole by 1,2,3-triazole resulted in a topological transformation of the parent framework from a sodalite (SOD) network to a diamond (DIA) network.

Original languageEnglish
Pages (from-to)2028-2031
Number of pages4
JournalChemical Communications
Volume53
Issue number12
DOIs
Publication statusPublished - 2017

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Triazoles
Diamonds
Substitution reactions
Ligands
Diamond
2-methylimidazole

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

From 2-methylimidazole to 1,2,3-triazole : a topological transformation of ZIF-8 and ZIF-67 by post-synthetic modification. / Erkartal, Mustafa; Erkilic, Ufuk; Tam, Benjamin; Usta, Hakan; Yazaydin, Ozgur; Hupp, Joseph T; Farha, Omar K.; Sen, Unal.

In: Chemical Communications, Vol. 53, No. 12, 2017, p. 2028-2031.

Research output: Contribution to journalArticle

Erkartal, Mustafa ; Erkilic, Ufuk ; Tam, Benjamin ; Usta, Hakan ; Yazaydin, Ozgur ; Hupp, Joseph T ; Farha, Omar K. ; Sen, Unal. / From 2-methylimidazole to 1,2,3-triazole : a topological transformation of ZIF-8 and ZIF-67 by post-synthetic modification. In: Chemical Communications. 2017 ; Vol. 53, No. 12. pp. 2028-2031.
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