From 2-methylimidazole to 1,2,3-triazole: a topological transformation of ZIF-8 and ZIF-67 by post-synthetic modification

Mustafa Erkartal; Ufuk Erkilic; Benjamin Tam; Hakan Usta; Ozgur Yazaydin; Joseph T. Hupp; Omar K. Farha; Unal Sen

doi:10.1039/c6cc08746a

From 2-methylimidazole to 1,2,3-triazole: a topological transformation of ZIF-8 and ZIF-67 by post-synthetic modification

Mustafa Erkartal, Ufuk Erkilic, Benjamin Tam, Hakan Usta, Ozgur Yazaydin, Joseph T. Hupp, Omar K. Farha, Unal Sen

Northwestern University

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

Bridging ligand replacement in zeolitic imidazolate frameworks, ZIF-8 and ZIF-67, by 1,2,3-triazole was investigated. A complete substitution of 2-methylimidazole by 1,2,3-triazole resulted in a topological transformation of the parent framework from a sodalite (SOD) network to a diamond (DIA) network.

Original language	English
Pages (from-to)	2028-2031
Number of pages	4
Journal	Chemical Communications
Volume	53
Issue number	12
DOIs	https://doi.org/10.1039/c6cc08746a
Publication status	Published - 2017

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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From 2-methylimidazole to 1,2,3-triazole : a topological transformation of ZIF-8 and ZIF-67 by post-synthetic modification. / Erkartal, Mustafa; Erkilic, Ufuk; Tam, Benjamin; Usta, Hakan; Yazaydin, Ozgur; Hupp, Joseph T.; Farha, Omar K.; Sen, Unal.

In: Chemical Communications, Vol. 53, No. 12, 2017, p. 2028-2031.

Research output: Contribution to journal › Article › peer-review

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abstract = "Bridging ligand replacement in zeolitic imidazolate frameworks, ZIF-8 and ZIF-67, by 1,2,3-triazole was investigated. A complete substitution of 2-methylimidazole by 1,2,3-triazole resulted in a topological transformation of the parent framework from a sodalite (SOD) network to a diamond (DIA) network.",

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AU - Tam, Benjamin

AU - Usta, Hakan

AU - Yazaydin, Ozgur

AU - Hupp, Joseph T.

AU - Farha, Omar K.

AU - Sen, Unal

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