Frontal analysis of product peaks from gas chromatographic reactors. Dicyclopentadiene and di-tert.-butyl peroxide decomposition

James E. Patton, Harold H Kung, Stanley H. Langer

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The chromatographic curve resulting from pulse injection of a reactant into a chromatographic column may contain significant information about products. Under some conditions, the elution volume or time at one-half the step height of the product curve approximates the characteristic elution volume, or time, of product material. This may even be true when reactants give several products. Such information may be used for product identification and obtaining solution thermodynamic data.

Original languageEnglish
Pages (from-to)73-79
Number of pages7
JournalJournal of Chromatography A
Volume104
Issue number1
DOIs
Publication statusPublished - Jan 29 1975

ASJC Scopus subject areas

  • Analytical Chemistry

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