Abstract
This perspective examines frustrated Lewis pairs (FLPs) in the context of heterolytic cleavage of H2 by transition metal complexes, with an emphasis on molecular complexes bearing an intramolecular Lewis base. FLPs have traditionally been associated with main group compounds, yet many reactions of transition metal complexes support a broader classification of FLPs that includes certain types of transition metal complexes with reactivity resembling main group-based FLPs. This article surveys transition metal complexes that heterolytically cleave H2, which vary in the degree that the Lewis pairs within these systems interact. Many of the examples include complexes bearing a pendant amine functioning as the base with the metal functioning as the hydride acceptor. Consideration of transition metal compounds in the context of FLPs can inspire new innovations and improvements in transition metal catalysis. This article is part of the themed issue 'Frustrated Lewis pair chemistry'.
| Original language | English |
|---|---|
| Article number | 20170002 |
| Journal | Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences |
| Volume | 375 |
| Issue number | 2101 |
| DOIs | |
| Publication status | Published - Aug 28 2017 |
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Keywords
- Cleavage
- Frustrated
- Heterolytic
- Hydride
- Hydrogen
- Hydrogenase
ASJC Scopus subject areas
- Mathematics(all)
- Engineering(all)
- Physics and Astronomy(all)
Cite this
Frustration across the periodic table : Heterolytic cleavage of dihydrogen by metal complexes. / Bullock, R Morris; Chambers, Geofrey M.
In: Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 375, No. 2101, 20170002, 28.08.2017.Research output: Contribution to journal › Review article
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TY - JOUR
T1 - Frustration across the periodic table
T2 - Heterolytic cleavage of dihydrogen by metal complexes
AU - Bullock, R Morris
AU - Chambers, Geofrey M.
PY - 2017/8/28
Y1 - 2017/8/28
N2 - This perspective examines frustrated Lewis pairs (FLPs) in the context of heterolytic cleavage of H2 by transition metal complexes, with an emphasis on molecular complexes bearing an intramolecular Lewis base. FLPs have traditionally been associated with main group compounds, yet many reactions of transition metal complexes support a broader classification of FLPs that includes certain types of transition metal complexes with reactivity resembling main group-based FLPs. This article surveys transition metal complexes that heterolytically cleave H2, which vary in the degree that the Lewis pairs within these systems interact. Many of the examples include complexes bearing a pendant amine functioning as the base with the metal functioning as the hydride acceptor. Consideration of transition metal compounds in the context of FLPs can inspire new innovations and improvements in transition metal catalysis. This article is part of the themed issue 'Frustrated Lewis pair chemistry'.
AB - This perspective examines frustrated Lewis pairs (FLPs) in the context of heterolytic cleavage of H2 by transition metal complexes, with an emphasis on molecular complexes bearing an intramolecular Lewis base. FLPs have traditionally been associated with main group compounds, yet many reactions of transition metal complexes support a broader classification of FLPs that includes certain types of transition metal complexes with reactivity resembling main group-based FLPs. This article surveys transition metal complexes that heterolytically cleave H2, which vary in the degree that the Lewis pairs within these systems interact. Many of the examples include complexes bearing a pendant amine functioning as the base with the metal functioning as the hydride acceptor. Consideration of transition metal compounds in the context of FLPs can inspire new innovations and improvements in transition metal catalysis. This article is part of the themed issue 'Frustrated Lewis pair chemistry'.
KW - Cleavage
KW - Frustrated
KW - Heterolytic
KW - Hydride
KW - Hydrogen
KW - Hydrogenase
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UR - http://www.scopus.com/inward/citedby.url?scp=85026262727&partnerID=8YFLogxK
U2 - 10.1098/rsta.2017.0002
DO - 10.1098/rsta.2017.0002
M3 - Review article
C2 - 28739961
AN - SCOPUS:85026262727
VL - 375
JO - Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences
JF - Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences
SN - 0962-8428
IS - 2101
M1 - 20170002
ER -