Gas-Phase Dimerization of Ethylene under Mild Conditions Catalyzed by MOF Materials Containing (bpy)NiII Complexes

Sherzod T. Madrahimov, James R. Gallagher, Guanghui Zhang, Zachary Meinhart, Sergio J. Garibay, Massimiliano Delferro, Jeffrey T. Miller, Omar K. Farha, Joseph T Hupp, Sonbinh T. Nguyen

Research output: Contribution to journalArticle

68 Citations (Scopus)

Abstract

NU-1000-(bpy)NiII, a highly porous MOF material possessing well-defined (bpy)NiII moieties, was prepared through solvent-assisted ligand incorporation (SALI). Treatment with Et2AlCl affords a single-site catalyst with excellent catalytic activity for ethylene dimerization (intrinsic activity for butenes that is up to an order of magnitude higher than the corresponding (bpy)NiCl2 homogeneous analogue) and stability (can be reused at least three times). The high porosity of this catalyst results in outstanding levels of activity at ambient temperature in gas-phase ethylene dimerization reactions, both under batch and continuous flow conditions.

Original languageEnglish
Pages (from-to)6713-6718
Number of pages6
JournalACS Catalysis
Volume5
Issue number11
DOIs
Publication statusPublished - Nov 6 2015

Fingerprint

Dimerization
Ethylene
Gases
Catalysts
Butenes
Porous materials
Catalyst activity
Thermodynamic properties
Porosity
Ligands
Temperature
ethylene
butylene

Keywords

  • (bipyridyl)nickel complexes
  • catalysis
  • ethylene dimerization
  • gas-phase reaction
  • metal-organic framework

ASJC Scopus subject areas

  • Catalysis

Cite this

Madrahimov, S. T., Gallagher, J. R., Zhang, G., Meinhart, Z., Garibay, S. J., Delferro, M., ... Nguyen, S. T. (2015). Gas-Phase Dimerization of Ethylene under Mild Conditions Catalyzed by MOF Materials Containing (bpy)NiII Complexes. ACS Catalysis, 5(11), 6713-6718. https://doi.org/10.1021/acscatal.5b01604

Gas-Phase Dimerization of Ethylene under Mild Conditions Catalyzed by MOF Materials Containing (bpy)NiII Complexes. / Madrahimov, Sherzod T.; Gallagher, James R.; Zhang, Guanghui; Meinhart, Zachary; Garibay, Sergio J.; Delferro, Massimiliano; Miller, Jeffrey T.; Farha, Omar K.; Hupp, Joseph T; Nguyen, Sonbinh T.

In: ACS Catalysis, Vol. 5, No. 11, 06.11.2015, p. 6713-6718.

Research output: Contribution to journalArticle

Madrahimov, ST, Gallagher, JR, Zhang, G, Meinhart, Z, Garibay, SJ, Delferro, M, Miller, JT, Farha, OK, Hupp, JT & Nguyen, ST 2015, 'Gas-Phase Dimerization of Ethylene under Mild Conditions Catalyzed by MOF Materials Containing (bpy)NiII Complexes', ACS Catalysis, vol. 5, no. 11, pp. 6713-6718. https://doi.org/10.1021/acscatal.5b01604
Madrahimov ST, Gallagher JR, Zhang G, Meinhart Z, Garibay SJ, Delferro M et al. Gas-Phase Dimerization of Ethylene under Mild Conditions Catalyzed by MOF Materials Containing (bpy)NiII Complexes. ACS Catalysis. 2015 Nov 6;5(11):6713-6718. https://doi.org/10.1021/acscatal.5b01604
Madrahimov, Sherzod T. ; Gallagher, James R. ; Zhang, Guanghui ; Meinhart, Zachary ; Garibay, Sergio J. ; Delferro, Massimiliano ; Miller, Jeffrey T. ; Farha, Omar K. ; Hupp, Joseph T ; Nguyen, Sonbinh T. / Gas-Phase Dimerization of Ethylene under Mild Conditions Catalyzed by MOF Materials Containing (bpy)NiII Complexes. In: ACS Catalysis. 2015 ; Vol. 5, No. 11. pp. 6713-6718.
@article{274e0fb0456e41cc91bf6ca0d268c50a,
title = "Gas-Phase Dimerization of Ethylene under Mild Conditions Catalyzed by MOF Materials Containing (bpy)NiII Complexes",
abstract = "NU-1000-(bpy)NiII, a highly porous MOF material possessing well-defined (bpy)NiII moieties, was prepared through solvent-assisted ligand incorporation (SALI). Treatment with Et2AlCl affords a single-site catalyst with excellent catalytic activity for ethylene dimerization (intrinsic activity for butenes that is up to an order of magnitude higher than the corresponding (bpy)NiCl2 homogeneous analogue) and stability (can be reused at least three times). The high porosity of this catalyst results in outstanding levels of activity at ambient temperature in gas-phase ethylene dimerization reactions, both under batch and continuous flow conditions.",
keywords = "(bipyridyl)nickel complexes, catalysis, ethylene dimerization, gas-phase reaction, metal-organic framework",
author = "Madrahimov, {Sherzod T.} and Gallagher, {James R.} and Guanghui Zhang and Zachary Meinhart and Garibay, {Sergio J.} and Massimiliano Delferro and Miller, {Jeffrey T.} and Farha, {Omar K.} and Hupp, {Joseph T} and Nguyen, {Sonbinh T.}",
year = "2015",
month = "11",
day = "6",
doi = "10.1021/acscatal.5b01604",
language = "English",
volume = "5",
pages = "6713--6718",
journal = "ACS Catalysis",
issn = "2155-5435",
publisher = "American Chemical Society",
number = "11",

}

TY - JOUR

T1 - Gas-Phase Dimerization of Ethylene under Mild Conditions Catalyzed by MOF Materials Containing (bpy)NiII Complexes

AU - Madrahimov, Sherzod T.

AU - Gallagher, James R.

AU - Zhang, Guanghui

AU - Meinhart, Zachary

AU - Garibay, Sergio J.

AU - Delferro, Massimiliano

AU - Miller, Jeffrey T.

AU - Farha, Omar K.

AU - Hupp, Joseph T

AU - Nguyen, Sonbinh T.

PY - 2015/11/6

Y1 - 2015/11/6

N2 - NU-1000-(bpy)NiII, a highly porous MOF material possessing well-defined (bpy)NiII moieties, was prepared through solvent-assisted ligand incorporation (SALI). Treatment with Et2AlCl affords a single-site catalyst with excellent catalytic activity for ethylene dimerization (intrinsic activity for butenes that is up to an order of magnitude higher than the corresponding (bpy)NiCl2 homogeneous analogue) and stability (can be reused at least three times). The high porosity of this catalyst results in outstanding levels of activity at ambient temperature in gas-phase ethylene dimerization reactions, both under batch and continuous flow conditions.

AB - NU-1000-(bpy)NiII, a highly porous MOF material possessing well-defined (bpy)NiII moieties, was prepared through solvent-assisted ligand incorporation (SALI). Treatment with Et2AlCl affords a single-site catalyst with excellent catalytic activity for ethylene dimerization (intrinsic activity for butenes that is up to an order of magnitude higher than the corresponding (bpy)NiCl2 homogeneous analogue) and stability (can be reused at least three times). The high porosity of this catalyst results in outstanding levels of activity at ambient temperature in gas-phase ethylene dimerization reactions, both under batch and continuous flow conditions.

KW - (bipyridyl)nickel complexes

KW - catalysis

KW - ethylene dimerization

KW - gas-phase reaction

KW - metal-organic framework

UR - http://www.scopus.com/inward/record.url?scp=84946782094&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84946782094&partnerID=8YFLogxK

U2 - 10.1021/acscatal.5b01604

DO - 10.1021/acscatal.5b01604

M3 - Article

AN - SCOPUS:84946782094

VL - 5

SP - 6713

EP - 6718

JO - ACS Catalysis

JF - ACS Catalysis

SN - 2155-5435

IS - 11

ER -