Abstract
(Chemical Equation Presented) Calming the radicals: Aminyl radicals may one day be useful oxidation catalysts if their thermodynamic instability can be overcome, for example, through complexation with a metal. The semiquinone-anilino-radical and catechol-anilino-radical complexes 1 and 2 have now been prepared and the anilino-radical character of the tetradentate amine ligand proved by electron paramagentic resonance and resonance Raman spectroscopy, as well as DFT calculations.
| Original language | English |
|---|---|
| Pages (from-to) | 5728-5730 |
| Number of pages | 3 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 46 |
| Issue number | 30 |
| DOIs | |
| Publication status | Published - Aug 3 2007 |
Keywords
- Anilino radicals
- Dioxolene ligands
- EPR spectroscopy
- Raman spectroscopy
- Ruthenium
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
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Cite this
Miyazato, Y., Wada, T., Muckerman, J. T., Fujita, E., & Tanaka, K. (2007). Generation of a RuII-semiquinone-anilino-radical complex through the deprotonation of a RuIII-semiquinone-anilido complex. Angewandte Chemie - International Edition, 46(30), 5728-5730. https://doi.org/10.1002/anie.200701600