Grain-Size-Limited Mobility in Methylammonium Lead Iodide Perovskite Thin Films

Obadiah G. Reid, Mengjin Yang, Nikos Kopidakis, Kai Zhu, Gary Rumbles

Research output: Contribution to journalArticle

64 Citations (Scopus)

Abstract

We report a systematic study of the gigahertz-frequency charge carrier mobility found in methylammonium lead iodide perovskite films as a function of average grain size using time-resolved microwave conductivity and a single processing chemistry. Our measurements are in good agreement with the Kubo formula for the AC mobility of charges confined within finite grains, suggesting (1) that the surface grains imaged via scanning electron microscopy are representative of the true electronic domain size and not substantially subdivided by twinning or other defects not visible by microscopy and (2) that the time scale of diffusive transport across grain boundaries is much slower than the period of the microwave field in this measurement (∼100 ps). The intrinsic (infinite grain size) minimum mobility extracted form the model is 29 ± 6 cm2 V-1 s-1 at the probe frequency (8.9 GHz).

Original languageEnglish
Pages (from-to)561-565
Number of pages5
JournalACS Energy Letters
Volume1
Issue number3
DOIs
Publication statusPublished - Sep 9 2016

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Iodides
Perovskite
Lead
Microwaves
Thin films
Carrier mobility
Twinning
Charge carriers
Microscopic examination
Grain boundaries
Defects
Scanning electron microscopy
Processing
methylamine
perovskite

ASJC Scopus subject areas

  • Chemistry (miscellaneous)
  • Renewable Energy, Sustainability and the Environment
  • Fuel Technology
  • Energy Engineering and Power Technology
  • Materials Chemistry

Cite this

Grain-Size-Limited Mobility in Methylammonium Lead Iodide Perovskite Thin Films. / Reid, Obadiah G.; Yang, Mengjin; Kopidakis, Nikos; Zhu, Kai; Rumbles, Gary.

In: ACS Energy Letters, Vol. 1, No. 3, 09.09.2016, p. 561-565.

Research output: Contribution to journalArticle

Reid, Obadiah G. ; Yang, Mengjin ; Kopidakis, Nikos ; Zhu, Kai ; Rumbles, Gary. / Grain-Size-Limited Mobility in Methylammonium Lead Iodide Perovskite Thin Films. In: ACS Energy Letters. 2016 ; Vol. 1, No. 3. pp. 561-565.
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