Group 6 dinitrogen complexes supported by diphosphine ligands containing proton relays: Toward the reduction of dinitrogen to ammonia

Michael T. Mock, Amy N. Groves, Charles J. Weiss, Shentan Chen, Roger Rousseau, Daniel L DuBois, R Morris Bullock

Research output: Chapter in Book/Report/Conference proceedingConference contribution


The reduction of dinitrogen to ammonia from N2 and H2 is currently carried out by the Haber-Bosch process, an energy intensive process that requires high pressures and high temperatures and accounts for the production of millions of tons of ammonia per year. The development of a catalytic, energy-efficient process for N2 reduction is of great interest and remains a formidable challenge. In our approach, we are developing "Chatt-type" ((P-P)2M(N2)2, P-P = diphosphine ligand) molecular electrocatalysts of the Group 6 metals (Cr, Mo, W), supported by diphosphine ligands containing non-coordinating pendant amines (e.g., PNP, (R2PCH2)2N(R′) and PR 2NR′ 2, substituted 1,5-diaza-3,7-diphosphacyclooctanes) to serve as proton relays. These studies are aimed at answering fundamental questions regarding the role of proton relays in the second coordination sphere of the complexes in their ability to facilitate proton movement from an external acid to metal-bound dinitrogen ligands in the challenging, multi-proton/electron reduction of N2 to ammonia.

Original languageEnglish
Title of host publicationACS National Meeting Book of Abstracts
Publication statusPublished - 2011
Event241st ACS National Meeting and Exposition - Anaheim, CA, United States
Duration: Mar 27 2011Mar 31 2011


Other241st ACS National Meeting and Exposition
CountryUnited States
CityAnaheim, CA


ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

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