Abstract
Facile control over the chemical polymerization of pyrrole from solutions of pyrrole-phosphomolybdic acid has allowed processibility of conducting poly(pyrrole). This approach has allowed thin conducting films of poly(pyrrole) to be deposited in a single step, and in contrast to electrochemical polymerization methods, is not limited to electrically conducting substrates. For example, 40-100 nm thick poly(pyrrole) films with conducivities in the range of 15 to 30 S cm-1 have been spin coated onto insulating glass substrates. Insight into the mechanism of polymerization has been obtained with cyclic voltammetry and UV-Vis spectroscopy.
| Original language | English |
|---|---|
| Pages (from-to) | 447-451 |
| Number of pages | 5 |
| Journal | Inorganica Chimica Acta |
| Volume | 240 |
| Issue number | 1-2 |
| DOIs | |
| Publication status | Published - 1995 |
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Keywords
- Conducting polymers
- Cyclic voltammetry
- Phosphomolybdate clusters
- Poly(pyrrole)
ASJC Scopus subject areas
- Inorganic Chemistry
- Physical and Theoretical Chemistry
- Materials Chemistry
Cite this
Growth of thin processable films of poly(pyrrole) using phosphomolybdate clusters. / Freund, Michael S.; Karp, Chris; Lewis, Nathan S.
In: Inorganica Chimica Acta, Vol. 240, No. 1-2, 1995, p. 447-451.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Growth of thin processable films of poly(pyrrole) using phosphomolybdate clusters
AU - Freund, Michael S.
AU - Karp, Chris
AU - Lewis, Nathan S
PY - 1995
Y1 - 1995
N2 - Facile control over the chemical polymerization of pyrrole from solutions of pyrrole-phosphomolybdic acid has allowed processibility of conducting poly(pyrrole). This approach has allowed thin conducting films of poly(pyrrole) to be deposited in a single step, and in contrast to electrochemical polymerization methods, is not limited to electrically conducting substrates. For example, 40-100 nm thick poly(pyrrole) films with conducivities in the range of 15 to 30 S cm-1 have been spin coated onto insulating glass substrates. Insight into the mechanism of polymerization has been obtained with cyclic voltammetry and UV-Vis spectroscopy.
AB - Facile control over the chemical polymerization of pyrrole from solutions of pyrrole-phosphomolybdic acid has allowed processibility of conducting poly(pyrrole). This approach has allowed thin conducting films of poly(pyrrole) to be deposited in a single step, and in contrast to electrochemical polymerization methods, is not limited to electrically conducting substrates. For example, 40-100 nm thick poly(pyrrole) films with conducivities in the range of 15 to 30 S cm-1 have been spin coated onto insulating glass substrates. Insight into the mechanism of polymerization has been obtained with cyclic voltammetry and UV-Vis spectroscopy.
KW - Conducting polymers
KW - Cyclic voltammetry
KW - Phosphomolybdate clusters
KW - Poly(pyrrole)
UR - http://www.scopus.com/inward/record.url?scp=0000009464&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0000009464&partnerID=8YFLogxK
U2 - 10.1016/0020-1693(95)04569-4
DO - 10.1016/0020-1693(95)04569-4
M3 - Article
AN - SCOPUS:0000009464
VL - 240
SP - 447
EP - 451
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
SN - 0020-1693
IS - 1-2
ER -