Heteroatom-Doped Carbon Materials for Hydrazine Oxidation

Tao Zhang, Teddy Asefa

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The key in designing efficient direct liquid fuel cells (DLFCs), which can offer some solutions to society's grand challenges associated with sustainability and energy future, currently lies in the development of cost-effective electrocatalysts. Among the many types of fuel cells, direct hydrazine fuel cells (DHFCs) are of particular interest, especially due to their high theoretical cell voltages and clean emission. However, DHFCs currently use noble-metal-based electrocatalysts, and the scarcity and high cost of noble metals are hindering these fuel cells from finding large-scale practical applications. In order to replace noble-metal-based electrocatalysts with sustainable ones and help DHFCs become widely usable, great efforts are being made to develop stable heteroatom (e.g., B, N, O, P and S)-doped carbon electrocatalysts, the activities of which are comparable to, or better than, those of noble metals. Here, the recent research progress and the advancements made on the development of heteroatom-doped carbon materials, their general properties, their electrocatalytic activities toward the HzOR, and their dopant- and structure-related electrocatalytic properties for the HzOR are summarized. Perspectives on the different directions that the research endeavors in this field need to take in the future and the challenges associated with DHFCs are included.

Original languageEnglish
Article number1804394
JournalAdvanced Materials
DOIs
Publication statusAccepted/In press - Jan 1 2018

Fingerprint

hydrazine
Hydrazine
Fuel cells
Carbon
Electrocatalysts
Oxidation
Precious metals
Liquid fuels
Costs
Sustainable development

Keywords

  • electrocatalysts
  • fuel cells
  • heteroatom-doped carbon
  • hydrazine oxidation reaction
  • metal-free catalysts

ASJC Scopus subject areas

  • Materials Science(all)
  • Mechanics of Materials
  • Mechanical Engineering

Cite this

Heteroatom-Doped Carbon Materials for Hydrazine Oxidation. / Zhang, Tao; Asefa, Teddy.

In: Advanced Materials, 01.01.2018.

Research output: Contribution to journalArticle

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