Heterobimetallic Compounds Linked by Heterodifunctional Ligands: Synthesis and X-ray Crystal Structure of [formula omitted]

Charles P. Casey; R. Morris Bullock; William C. Fultz; Arnold L. Rheingold

doi:10.1021/om00072a008

Heterobimetallic Compounds Linked by Heterodifunctional Ligands: Synthesis and X-ray Crystal Structure of [formula omitted]

Charles P. Casey, R. Morris Bullock, William C. Fultz, Arnold L. Rheingold

Pacific Northwest National Laboratory

Research output: Contribution to journal › Article › peer-review

86 Citations (Scopus)

Abstract

Three new heterobimetallic compounds, [formula omitted], and [formula omitted], 3, have been prepared. 1 was prepared by reaction of Li+[η⁵-C₅H₄P(C₆H₆)₂]Mo(CO)₃⁻, 4, with [(CO)₄MnBr]₂. Similarly, 2 was prepared by reacting Li⁺[η⁵-C₅H₄P(C₆H₄-p-CH₃)₂]Mo(CO)₃⁻, 5, with [(CO)₄MnBr]₂, and 3 was prepared from 5 and (CO)₄ReBr]₂. 1 was structurally characterized by X-ray crystallography. 1 crystallizes in the space group Pbca [D_2h¹⁵] with Z = 8 and orthorhombic unit cell dimensions of a = 11.782 (2) Å, b = 17.215 (3) Å, and c = 23.129 (6) Å. The Mo-Mn bond length is 3.054 (1) Å.

Original language	English
Pages (from-to)	1591-1596
Number of pages	6
Journal	Organometallics
Volume	1
Issue number	12
DOIs	https://doi.org/10.1021/om00072a008
Publication status	Published - 1982

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

Access to Document

10.1021/om00072a008

Fingerprint Dive into the research topics of 'Heterobimetallic Compounds Linked by Heterodifunctional Ligands: Synthesis and X-ray Crystal Structure of [formula omitted]'. Together they form a unique fingerprint.

Cite this

@article{e5f6da5912cf48378fce590e656bcbb5,

title = "Heterobimetallic Compounds Linked by Heterodifunctional Ligands: Synthesis and X-ray Crystal Structure of [formula omitted]",

abstract = "Three new heterobimetallic compounds, [formula omitted], and [formula omitted], 3, have been prepared. 1 was prepared by reaction of Li+[η5-C5H4P(C6H6)2]Mo(CO)3−, 4, with [(CO)4MnBr]2. Similarly, 2 was prepared by reacting Li+[η5-C5H4P(C6H4-p-CH3)2]Mo(CO)3−, 5, with [(CO)4MnBr]2, and 3 was prepared from 5 and (CO)4ReBr]2. 1 was structurally characterized by X-ray crystallography. 1 crystallizes in the space group Pbca [D2h15] with Z = 8 and orthorhombic unit cell dimensions of a = 11.782 (2) {\AA}, b = 17.215 (3) {\AA}, and c = 23.129 (6) {\AA}. The Mo-Mn bond length is 3.054 (1) {\AA}.",

author = "Casey, {Charles P.} and Bullock, {R. Morris} and Fultz, {William C.} and Rheingold, {Arnold L.}",

year = "1982",

doi = "10.1021/om00072a008",

language = "English",

volume = "1",

pages = "1591--1596",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "12",

}

TY - JOUR

T1 - Heterobimetallic Compounds Linked by Heterodifunctional Ligands

T2 - Synthesis and X-ray Crystal Structure of [formula omitted]

AU - Casey, Charles P.

AU - Bullock, R. Morris

AU - Fultz, William C.

AU - Rheingold, Arnold L.

PY - 1982

Y1 - 1982

N2 - Three new heterobimetallic compounds, [formula omitted], and [formula omitted], 3, have been prepared. 1 was prepared by reaction of Li+[η5-C5H4P(C6H6)2]Mo(CO)3−, 4, with [(CO)4MnBr]2. Similarly, 2 was prepared by reacting Li+[η5-C5H4P(C6H4-p-CH3)2]Mo(CO)3−, 5, with [(CO)4MnBr]2, and 3 was prepared from 5 and (CO)4ReBr]2. 1 was structurally characterized by X-ray crystallography. 1 crystallizes in the space group Pbca [D2h15] with Z = 8 and orthorhombic unit cell dimensions of a = 11.782 (2) Å, b = 17.215 (3) Å, and c = 23.129 (6) Å. The Mo-Mn bond length is 3.054 (1) Å.

AB - Three new heterobimetallic compounds, [formula omitted], and [formula omitted], 3, have been prepared. 1 was prepared by reaction of Li+[η5-C5H4P(C6H6)2]Mo(CO)3−, 4, with [(CO)4MnBr]2. Similarly, 2 was prepared by reacting Li+[η5-C5H4P(C6H4-p-CH3)2]Mo(CO)3−, 5, with [(CO)4MnBr]2, and 3 was prepared from 5 and (CO)4ReBr]2. 1 was structurally characterized by X-ray crystallography. 1 crystallizes in the space group Pbca [D2h15] with Z = 8 and orthorhombic unit cell dimensions of a = 11.782 (2) Å, b = 17.215 (3) Å, and c = 23.129 (6) Å. The Mo-Mn bond length is 3.054 (1) Å.

UR - http://www.scopus.com/inward/record.url?scp=0000747732&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0000747732&partnerID=8YFLogxK

U2 - 10.1021/om00072a008

DO - 10.1021/om00072a008

M3 - Article

AN - SCOPUS:0000747732

VL - 1

SP - 1591

EP - 1596

JO - Organometallics

JF - Organometallics

SN - 0276-7333

IS - 12

ER -