TY - JOUR
T1 - Heterobimetallic Compounds Linked by Heterodifunctional Ligands
T2 - Synthesis and X-ray Crystal Structure of [formula omitted]
AU - Casey, Charles P.
AU - Bullock, R. Morris
AU - Fultz, William C.
AU - Rheingold, Arnold L.
PY - 1982
Y1 - 1982
N2 - Three new heterobimetallic compounds, [formula omitted], and [formula omitted], 3, have been prepared. 1 was prepared by reaction of Li+[η5-C5H4P(C6H6)2]Mo(CO)3−, 4, with [(CO)4MnBr]2. Similarly, 2 was prepared by reacting Li+[η5-C5H4P(C6H4-p-CH3)2]Mo(CO)3−, 5, with [(CO)4MnBr]2, and 3 was prepared from 5 and (CO)4ReBr]2. 1 was structurally characterized by X-ray crystallography. 1 crystallizes in the space group Pbca [D2h15] with Z = 8 and orthorhombic unit cell dimensions of a = 11.782 (2) Å, b = 17.215 (3) Å, and c = 23.129 (6) Å. The Mo-Mn bond length is 3.054 (1) Å.
AB - Three new heterobimetallic compounds, [formula omitted], and [formula omitted], 3, have been prepared. 1 was prepared by reaction of Li+[η5-C5H4P(C6H6)2]Mo(CO)3−, 4, with [(CO)4MnBr]2. Similarly, 2 was prepared by reacting Li+[η5-C5H4P(C6H4-p-CH3)2]Mo(CO)3−, 5, with [(CO)4MnBr]2, and 3 was prepared from 5 and (CO)4ReBr]2. 1 was structurally characterized by X-ray crystallography. 1 crystallizes in the space group Pbca [D2h15] with Z = 8 and orthorhombic unit cell dimensions of a = 11.782 (2) Å, b = 17.215 (3) Å, and c = 23.129 (6) Å. The Mo-Mn bond length is 3.054 (1) Å.
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U2 - 10.1021/om00072a008
DO - 10.1021/om00072a008
M3 - Article
AN - SCOPUS:0000747732
VL - 1
SP - 1591
EP - 1596
JO - Organometallics
JF - Organometallics
SN - 0276-7333
IS - 12
ER -