Abstract
Three new heterobimetallic compounds, (CO)4MnMo(CO)3[η5-C5H 4P(C6H5)2], 1, (CO)4MnMo(CO)3-[η5-C5H 4P(C6H4-p-CH3)2], 2, and (CO)4ReMo(CO)3[η5-C5H 4P(C6H4-p-CH3)2], 3, have been prepared. 1 was prepared by reaction of Li+[η5-C5H4P(C6H 5)2]Mo(CO)3 -, 4, with [(CO)4MnBr]2. Similarly, 2 was prepared by reacting Li+[η5-C5H4P(C6H 4-p-CH3)2]Mo(CO)3 -, 5, with [(CO)4MnBr]2, and 3 was prepared from 5 and [(CO)4ReBr]2. 1 was structurally characterized by X-ray crystallography. 1 crystallizes in the space group Pbca [D2h 15] with Z = 8 and orthorhombic unit cell dimensions of a = 11.782 (2) Å, b = 17.215 (3) Å, and c = 23.129 (6) Å. The Mo-Mn bond length is 3.054 (1) Å.
| Original language | English |
|---|---|
| Pages (from-to) | 1591-1596 |
| Number of pages | 6 |
| Journal | Organometallics |
| Volume | 1 |
| Issue number | 12 |
| Publication status | Published - 1982 |
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ASJC Scopus subject areas
- Inorganic Chemistry
- Organic Chemistry
Cite this
Heterobimetallic compounds linked by heterodifunctional ligands : Synthesis and X-ray crystal structure of (CO)4MnMo(CO)3[η5-C5H 4P(C6H5)2]. / Casey, Charles P.; Bullock, R Morris; Fultz, William C.; Rheingold, Arnold L.
In: Organometallics, Vol. 1, No. 12, 1982, p. 1591-1596.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Heterobimetallic compounds linked by heterodifunctional ligands
T2 - Synthesis and X-ray crystal structure of (CO)4MnMo(CO)3[η5-C5H 4P(C6H5)2]
AU - Casey, Charles P.
AU - Bullock, R Morris
AU - Fultz, William C.
AU - Rheingold, Arnold L.
PY - 1982
Y1 - 1982
N2 - Three new heterobimetallic compounds, (CO)4MnMo(CO)3[η5-C5H 4P(C6H5)2], 1, (CO)4MnMo(CO)3-[η5-C5H 4P(C6H4-p-CH3)2], 2, and (CO)4ReMo(CO)3[η5-C5H 4P(C6H4-p-CH3)2], 3, have been prepared. 1 was prepared by reaction of Li+[η5-C5H4P(C6H 5)2]Mo(CO)3 -, 4, with [(CO)4MnBr]2. Similarly, 2 was prepared by reacting Li+[η5-C5H4P(C6H 4-p-CH3)2]Mo(CO)3 -, 5, with [(CO)4MnBr]2, and 3 was prepared from 5 and [(CO)4ReBr]2. 1 was structurally characterized by X-ray crystallography. 1 crystallizes in the space group Pbca [D2h 15] with Z = 8 and orthorhombic unit cell dimensions of a = 11.782 (2) Å, b = 17.215 (3) Å, and c = 23.129 (6) Å. The Mo-Mn bond length is 3.054 (1) Å.
AB - Three new heterobimetallic compounds, (CO)4MnMo(CO)3[η5-C5H 4P(C6H5)2], 1, (CO)4MnMo(CO)3-[η5-C5H 4P(C6H4-p-CH3)2], 2, and (CO)4ReMo(CO)3[η5-C5H 4P(C6H4-p-CH3)2], 3, have been prepared. 1 was prepared by reaction of Li+[η5-C5H4P(C6H 5)2]Mo(CO)3 -, 4, with [(CO)4MnBr]2. Similarly, 2 was prepared by reacting Li+[η5-C5H4P(C6H 4-p-CH3)2]Mo(CO)3 -, 5, with [(CO)4MnBr]2, and 3 was prepared from 5 and [(CO)4ReBr]2. 1 was structurally characterized by X-ray crystallography. 1 crystallizes in the space group Pbca [D2h 15] with Z = 8 and orthorhombic unit cell dimensions of a = 11.782 (2) Å, b = 17.215 (3) Å, and c = 23.129 (6) Å. The Mo-Mn bond length is 3.054 (1) Å.
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M3 - Article
AN - SCOPUS:0000747732
VL - 1
SP - 1591
EP - 1596
JO - Organometallics
JF - Organometallics
SN - 0276-7333
IS - 12
ER -