Heterobimetallic Compounds Linked by Heterodifunctional Ligands: Synthesis and X-ray Crystal Structure of [formula omitted]

Charles P. Casey, R. Morris Bullock, William C. Fultz, Arnold L. Rheingold

Research output: Contribution to journalArticle

86 Citations (Scopus)

Abstract

Three new heterobimetallic compounds, [formula omitted], and [formula omitted], 3, have been prepared. 1 was prepared by reaction of Li+[η5-C5H4P(C6H6)2]Mo(CO)3, 4, with [(CO)4MnBr]2. Similarly, 2 was prepared by reacting Li+5-C5H4P(C6H4-p-CH3)2]Mo(CO)3, 5, with [(CO)4MnBr]2, and 3 was prepared from 5 and (CO)4ReBr]2. 1 was structurally characterized by X-ray crystallography. 1 crystallizes in the space group Pbca [D2h15] with Z = 8 and orthorhombic unit cell dimensions of a = 11.782 (2) Å, b = 17.215 (3) Å, and c = 23.129 (6) Å. The Mo-Mn bond length is 3.054 (1) Å.

Original languageEnglish
Pages (from-to)1591-1596
Number of pages6
JournalOrganometallics
Volume1
Issue number12
DOIs
Publication statusPublished - 1982

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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