High performance Na-doped PbTe-PbS thermoelectric materials: Electronic density of states modification and shape-controlled nanostructures

Steven N. Girard, Jiaqing He, Xiaoyuan Zhou, Daniel Shoemaker, Christopher M. Jaworski, Ctirad Uher, Vinayak P. Dravid, Joseph P. Heremans, Mercouri G Kanatzidis

Research output: Contribution to journalArticle

217 Citations (Scopus)

Abstract

Thermoelectric heat-to-power generation is an attractive option for robust and environmentally friendly renewable energy production. Historically, the performance of thermoelectric materials has been limited by low efficiencies, related to the thermoelectric figure-of-merit ZT. Nanostructuring thermoelectric materials have shown to enhance ZT primarily via increasing phonon scattering, beneficially reducing lattice thermal conductivity. Conversely, density-of-states (DOS) engineering has also enhanced electronic transport properties. However, successfully joining the two approaches has proved elusive. Herein, we report a thermoelectric materials system whereby we can control both nanostructure formations to effectively reduce thermal conductivity, while concurrently modifying the electronic structure to significantly enhance thermoelectric power factor. We report that the thermoelectric system PbTe-PbS 12% doped with 2% Na produces shape-controlled cubic PbS nanostructures, which help reduce lattice thermal conductivity, while altering the solubility of PbS within the PbTe matrix beneficially modifies the DOS that allow for enhancements in thermoelectric power factor. These concomitant and synergistic effects result in a maximum ZT for 2% Na-doped PbTe-PbS 12% of 1.8 at 800 K.

Original languageEnglish
Pages (from-to)16588-16597
Number of pages10
JournalJournal of the American Chemical Society
Volume133
Issue number41
DOIs
Publication statusPublished - Oct 19 2011

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Thermal Conductivity
Electronic density of states
Nanostructures
Thermal conductivity
Thermoelectric power
Phonons
Renewable Energy
Phonon scattering
Joining
Transport properties
Solubility
Power generation
Electronic structure
Hot Temperature

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

High performance Na-doped PbTe-PbS thermoelectric materials : Electronic density of states modification and shape-controlled nanostructures. / Girard, Steven N.; He, Jiaqing; Zhou, Xiaoyuan; Shoemaker, Daniel; Jaworski, Christopher M.; Uher, Ctirad; Dravid, Vinayak P.; Heremans, Joseph P.; Kanatzidis, Mercouri G.

In: Journal of the American Chemical Society, Vol. 133, No. 41, 19.10.2011, p. 16588-16597.

Research output: Contribution to journalArticle

Girard, Steven N. ; He, Jiaqing ; Zhou, Xiaoyuan ; Shoemaker, Daniel ; Jaworski, Christopher M. ; Uher, Ctirad ; Dravid, Vinayak P. ; Heremans, Joseph P. ; Kanatzidis, Mercouri G. / High performance Na-doped PbTe-PbS thermoelectric materials : Electronic density of states modification and shape-controlled nanostructures. In: Journal of the American Chemical Society. 2011 ; Vol. 133, No. 41. pp. 16588-16597.
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