High-performance solution-processed amorphous zinc-indium-tin oxide thin-film transistors

Myung Gil Kim, Hyun Sung Kim, Young Geun Ha, Jiaqing He, Mercouri G Kanatzidis, Antonio Facchetti, Tobin J Marks

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193 Citations (Scopus)

Abstract

Films of the high-performance solution-processed amorphous oxide semiconductor a-ZnIn4Sn4O15, grown from 2-methoxyethanol/ethanolamine solutions, were used to fabricate thin-film transistors (TFTs) in combination with an organic self-assembled nanodielectric as the gate insulator. This structurally dense-packed semiconductor composition with minimal Zn2+ incorporation strongly suppresses transistor off-currents without significant mobility degradation, and affords field-effect electron mobilities of ∼90 cm2 V-1 s-1 (104 cm2 V-1 s-1 maximum obtained for patterned ZITO films), with Ion/Ioff ratio ∼105, a subthreshhold swing of ∼0.2 V/dec, and operating voltage 9-2xIn xSnxO9+1.5x (x = 1-4) and ZnIn 8-xSnxO13+0.5x (x = 1-7) were systematically investigated to elucidate those factors which yield optimum mobility, I on/Ioff, and threshold voltage parameters. It is shown that structural relaxation and densification by In3+ and Sn 4+ mixing is effective in reducing carrier trap sites and in creating carrier-generating oxygen vacancies. In contrast to the above results for TFTs fabricated with the organic self-assembled nanodielectric, ZnIn 4Sn4O15 TFTs fabricated with SiO2 gate insulators exhibit electron mobilities of only ∼11 cm2 V-1 s-1 with Ion/Ioff ratios ∼105, and a subthreshhold swing of ∼9.5 V/dec.

Original languageEnglish
Pages (from-to)10352-10364
Number of pages13
JournalJournal of the American Chemical Society
Volume132
Issue number30
DOIs
Publication statusPublished - Aug 4 2010

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ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Biochemistry
  • Colloid and Surface Chemistry

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