Abstract
Perovskite structure can be stabilized through high pressure (HP) synthesis. To illustrate this, the HP synthesis of a new copper-rich layered perovskite, La4Cu3MoO12, which is isotopic with La2CuSnO6 is discussed. When synthesized at ambient pressure, this perovskite forms a structure with remarkably low and unusual coordination of the constituents, which after treatment at high pressure and high temperature adopts new perovskite structure that contains unmixed copper-oxygen planes linked by mixed copper/molybdenum-oxygen planes.
| Original language | English |
|---|---|
| Pages (from-to) | 11518-11519 |
| Number of pages | 2 |
| Journal | Journal of the American Chemical Society |
| Volume | 120 |
| Issue number | 44 |
| DOIs | |
| Publication status | Published - Nov 11 1998 |
Fingerprint
ASJC Scopus subject areas
- Chemistry(all)
Cite this
High pressure transformation of La4Cu3MoO12 to a layered perovskite [5]. / Vander Griend, D. A.; Boudin, S.; Poeppelmeier, Kenneth R; Azuma, M.; Toganoh, H.; Takano, M.
In: Journal of the American Chemical Society, Vol. 120, No. 44, 11.11.1998, p. 11518-11519.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - High pressure transformation of La4Cu3MoO12 to a layered perovskite [5]
AU - Vander Griend, D. A.
AU - Boudin, S.
AU - Poeppelmeier, Kenneth R
AU - Azuma, M.
AU - Toganoh, H.
AU - Takano, M.
PY - 1998/11/11
Y1 - 1998/11/11
N2 - Perovskite structure can be stabilized through high pressure (HP) synthesis. To illustrate this, the HP synthesis of a new copper-rich layered perovskite, La4Cu3MoO12, which is isotopic with La2CuSnO6 is discussed. When synthesized at ambient pressure, this perovskite forms a structure with remarkably low and unusual coordination of the constituents, which after treatment at high pressure and high temperature adopts new perovskite structure that contains unmixed copper-oxygen planes linked by mixed copper/molybdenum-oxygen planes.
AB - Perovskite structure can be stabilized through high pressure (HP) synthesis. To illustrate this, the HP synthesis of a new copper-rich layered perovskite, La4Cu3MoO12, which is isotopic with La2CuSnO6 is discussed. When synthesized at ambient pressure, this perovskite forms a structure with remarkably low and unusual coordination of the constituents, which after treatment at high pressure and high temperature adopts new perovskite structure that contains unmixed copper-oxygen planes linked by mixed copper/molybdenum-oxygen planes.
UR - http://www.scopus.com/inward/record.url?scp=0032508950&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0032508950&partnerID=8YFLogxK
U2 - 10.1021/ja982259b
DO - 10.1021/ja982259b
M3 - Article
AN - SCOPUS:0032508950
VL - 120
SP - 11518
EP - 11519
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 44
ER -