High pressure transformation of La4Cu3MoO12 to a layered perovskite [5]

D. A. Vander Griend; S. Boudin; Kenneth R Poeppelmeier; M. Azuma; H. Toganoh; M. Takano

doi:10.1021/ja982259b

High pressure transformation of La₄Cu₃MoO₁₂ to a layered perovskite [5]

D. A. Vander Griend, S. Boudin, Kenneth R Poeppelmeier, M. Azuma, H. Toganoh, M. Takano

Northwestern University

Research output: Contribution to journal › Article

12 Citations (Scopus)

Abstract

Perovskite structure can be stabilized through high pressure (HP) synthesis. To illustrate this, the HP synthesis of a new copper-rich layered perovskite, La₄Cu₃MoO₁₂, which is isotopic with La₂CuSnO₆ is discussed. When synthesized at ambient pressure, this perovskite forms a structure with remarkably low and unusual coordination of the constituents, which after treatment at high pressure and high temperature adopts new perovskite structure that contains unmixed copper-oxygen planes linked by mixed copper/molybdenum-oxygen planes.

Original language	English
Pages (from-to)	11518-11519
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	120
Issue number	44
DOIs	https://doi.org/10.1021/ja982259b
Publication status	Published - Nov 11 1998

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Chemistry(all)

Cite this

Vander Griend, D. A., Boudin, S., Poeppelmeier, K. R., Azuma, M., Toganoh, H., & Takano, M. (1998). High pressure transformation of La₄Cu₃MoO₁₂ to a layered perovskite [5]. Journal of the American Chemical Society, 120(44), 11518-11519. https://doi.org/10.1021/ja982259b

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abstract = "Perovskite structure can be stabilized through high pressure (HP) synthesis. To illustrate this, the HP synthesis of a new copper-rich layered perovskite, La4Cu3MoO12, which is isotopic with La2CuSnO6 is discussed. When synthesized at ambient pressure, this perovskite forms a structure with remarkably low and unusual coordination of the constituents, which after treatment at high pressure and high temperature adopts new perovskite structure that contains unmixed copper-oxygen planes linked by mixed copper/molybdenum-oxygen planes.",

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AU - Toganoh, H.

AU - Takano, M.

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10.1021/ja982259b