High pressure transformation of La4Cu3MoO12 to a layered perovskite [5]

D. A. Vander Griend, S. Boudin, Kenneth R Poeppelmeier, M. Azuma, H. Toganoh, M. Takano

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Abstract

Perovskite structure can be stabilized through high pressure (HP) synthesis. To illustrate this, the HP synthesis of a new copper-rich layered perovskite, La4Cu3MoO12, which is isotopic with La2CuSnO6 is discussed. When synthesized at ambient pressure, this perovskite forms a structure with remarkably low and unusual coordination of the constituents, which after treatment at high pressure and high temperature adopts new perovskite structure that contains unmixed copper-oxygen planes linked by mixed copper/molybdenum-oxygen planes.

Original languageEnglish
Pages (from-to)11518-11519
Number of pages2
JournalJournal of the American Chemical Society
Volume120
Issue number44
DOIs
Publication statusPublished - Nov 11 1998

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Perovskite
Pressure
Copper
Oxygen
Molybdenum
Temperature
perovskite

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

High pressure transformation of La4Cu3MoO12 to a layered perovskite [5]. / Vander Griend, D. A.; Boudin, S.; Poeppelmeier, Kenneth R; Azuma, M.; Toganoh, H.; Takano, M.

In: Journal of the American Chemical Society, Vol. 120, No. 44, 11.11.1998, p. 11518-11519.

Research output: Contribution to journalArticle

Vander Griend, DA, Boudin, S, Poeppelmeier, KR, Azuma, M, Toganoh, H & Takano, M 1998, 'High pressure transformation of La4Cu3MoO12 to a layered perovskite [5]', Journal of the American Chemical Society, vol. 120, no. 44, pp. 11518-11519. https://doi.org/10.1021/ja982259b
Vander Griend, D. A. ; Boudin, S. ; Poeppelmeier, Kenneth R ; Azuma, M. ; Toganoh, H. ; Takano, M. / High pressure transformation of La4Cu3MoO12 to a layered perovskite [5]. In: Journal of the American Chemical Society. 1998 ; Vol. 120, No. 44. pp. 11518-11519.
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