High pressure transformation of La4Cu3MoO12 to a layered perovskite [5]

D. A. Vander Griend; S. Boudin; Kenneth R Poeppelmeier; M. Azuma; H. Toganoh; M. Takano

doi:10.1021/ja982259b

High pressure transformation of La₄Cu₃MoO₁₂ to a layered perovskite [5]

D. A. Vander Griend, S. Boudin, Kenneth R Poeppelmeier, M. Azuma, H. Toganoh, M. Takano

Northwestern University

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

Perovskite structure can be stabilized through high pressure (HP) synthesis. To illustrate this, the HP synthesis of a new copper-rich layered perovskite, La₄Cu₃MoO₁₂, which is isotopic with La₂CuSnO₆ is discussed. When synthesized at ambient pressure, this perovskite forms a structure with remarkably low and unusual coordination of the constituents, which after treatment at high pressure and high temperature adopts new perovskite structure that contains unmixed copper-oxygen planes linked by mixed copper/molybdenum-oxygen planes.

Original language	English
Pages (from-to)	11518-11519
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	120
Issue number	44
DOIs	https://doi.org/10.1021/ja982259b
Publication status	Published - Nov 11 1998

ASJC Scopus subject areas

Chemistry(all)

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10.1021/ja982259b

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title = "High pressure transformation of La4Cu3MoO12 to a layered perovskite [5]",

abstract = "Perovskite structure can be stabilized through high pressure (HP) synthesis. To illustrate this, the HP synthesis of a new copper-rich layered perovskite, La4Cu3MoO12, which is isotopic with La2CuSnO6 is discussed. When synthesized at ambient pressure, this perovskite forms a structure with remarkably low and unusual coordination of the constituents, which after treatment at high pressure and high temperature adopts new perovskite structure that contains unmixed copper-oxygen planes linked by mixed copper/molybdenum-oxygen planes.",

author = "{Vander Griend}, {D. A.} and S. Boudin and Poeppelmeier, {Kenneth R} and M. Azuma and H. Toganoh and M. Takano",

year = "1998",

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T1 - High pressure transformation of La4Cu3MoO12 to a layered perovskite [5]

AU - Vander Griend, D. A.

AU - Boudin, S.

AU - Poeppelmeier, Kenneth R

AU - Azuma, M.

AU - Toganoh, H.

AU - Takano, M.

PY - 1998/11/11

Y1 - 1998/11/11

N2 - Perovskite structure can be stabilized through high pressure (HP) synthesis. To illustrate this, the HP synthesis of a new copper-rich layered perovskite, La4Cu3MoO12, which is isotopic with La2CuSnO6 is discussed. When synthesized at ambient pressure, this perovskite forms a structure with remarkably low and unusual coordination of the constituents, which after treatment at high pressure and high temperature adopts new perovskite structure that contains unmixed copper-oxygen planes linked by mixed copper/molybdenum-oxygen planes.

AB - Perovskite structure can be stabilized through high pressure (HP) synthesis. To illustrate this, the HP synthesis of a new copper-rich layered perovskite, La4Cu3MoO12, which is isotopic with La2CuSnO6 is discussed. When synthesized at ambient pressure, this perovskite forms a structure with remarkably low and unusual coordination of the constituents, which after treatment at high pressure and high temperature adopts new perovskite structure that contains unmixed copper-oxygen planes linked by mixed copper/molybdenum-oxygen planes.

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