TY - JOUR
T1 - High pressure transformation of La4Cu3MoO12 to a layered perovskite [5]
AU - Vander Griend, D. A.
AU - Boudin, S.
AU - Poeppelmeier, Kenneth R
AU - Azuma, M.
AU - Toganoh, H.
AU - Takano, M.
PY - 1998/11/11
Y1 - 1998/11/11
N2 - Perovskite structure can be stabilized through high pressure (HP) synthesis. To illustrate this, the HP synthesis of a new copper-rich layered perovskite, La4Cu3MoO12, which is isotopic with La2CuSnO6 is discussed. When synthesized at ambient pressure, this perovskite forms a structure with remarkably low and unusual coordination of the constituents, which after treatment at high pressure and high temperature adopts new perovskite structure that contains unmixed copper-oxygen planes linked by mixed copper/molybdenum-oxygen planes.
AB - Perovskite structure can be stabilized through high pressure (HP) synthesis. To illustrate this, the HP synthesis of a new copper-rich layered perovskite, La4Cu3MoO12, which is isotopic with La2CuSnO6 is discussed. When synthesized at ambient pressure, this perovskite forms a structure with remarkably low and unusual coordination of the constituents, which after treatment at high pressure and high temperature adopts new perovskite structure that contains unmixed copper-oxygen planes linked by mixed copper/molybdenum-oxygen planes.
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U2 - 10.1021/ja982259b
DO - 10.1021/ja982259b
M3 - Article
AN - SCOPUS:0032508950
VL - 120
SP - 11518
EP - 11519
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 44
ER -