High pressure transformation of La4Cu3MoO12 to a layered perovskite [5]

D. A. Vander Griend, S. Boudin, Kenneth R Poeppelmeier, M. Azuma, H. Toganoh, M. Takano

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

Perovskite structure can be stabilized through high pressure (HP) synthesis. To illustrate this, the HP synthesis of a new copper-rich layered perovskite, La4Cu3MoO12, which is isotopic with La2CuSnO6 is discussed. When synthesized at ambient pressure, this perovskite forms a structure with remarkably low and unusual coordination of the constituents, which after treatment at high pressure and high temperature adopts new perovskite structure that contains unmixed copper-oxygen planes linked by mixed copper/molybdenum-oxygen planes.

Original languageEnglish
Pages (from-to)11518-11519
Number of pages2
JournalJournal of the American Chemical Society
Volume120
Issue number44
DOIs
Publication statusPublished - Nov 11 1998

ASJC Scopus subject areas

  • Chemistry(all)

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