High propene/propane selectivity in isostructural metal-organic frameworks with high densities of open metal sites

Youn Sang Bae, Chang Yeon Lee, Ki Chul Kim, Omar K. Farha, Peter Nickias, Joseph T Hupp, Sonbinh T. Nguyen, Randall Q. Snurr

Research output: Contribution to journalArticle

251 Citations (Scopus)

Abstract

Two go in, one comes out: A series of isostructural M-MOF-74 materials (M=Co, Mn, and Mg) with high densities of open metal sites have been examined for the selective adsorption of propene over propane. Co-MOF-74 exhibits the highest thermodynamic C 3H 6/C 3H 8 selectivity (ca. 45) reported for any MOF to date.

Original languageEnglish
Pages (from-to)1857-1860
Number of pages4
JournalAngewandte Chemie - International Edition
Volume51
Issue number8
DOIs
Publication statusPublished - Feb 20 2012

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Propane
Propylene
Metals
Thermodynamics
Adsorption
propylene

Keywords

  • adsorption
  • metal-organic frameworks
  • open metal sites
  • propane
  • propene

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis

Cite this

High propene/propane selectivity in isostructural metal-organic frameworks with high densities of open metal sites. / Bae, Youn Sang; Lee, Chang Yeon; Kim, Ki Chul; Farha, Omar K.; Nickias, Peter; Hupp, Joseph T; Nguyen, Sonbinh T.; Snurr, Randall Q.

In: Angewandte Chemie - International Edition, Vol. 51, No. 8, 20.02.2012, p. 1857-1860.

Research output: Contribution to journalArticle

Bae, Youn Sang ; Lee, Chang Yeon ; Kim, Ki Chul ; Farha, Omar K. ; Nickias, Peter ; Hupp, Joseph T ; Nguyen, Sonbinh T. ; Snurr, Randall Q. / High propene/propane selectivity in isostructural metal-organic frameworks with high densities of open metal sites. In: Angewandte Chemie - International Edition. 2012 ; Vol. 51, No. 8. pp. 1857-1860.
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