High thermoelectric figure of merit and improved mechanical properties in melt quenched PbTe-Ge and PbTe- Ge1-x Six eutectic and hypereutectic composites

Joseph R. Sootsman, Jiaqing He, Vinayak P. Dravid, Chang Peng Li, Ctirad Uher, Mercouri G Kanatzidis

Research output: Contribution to journalArticle

39 Citations (Scopus)

Abstract

We report the synthesis, microstructure, and transport properties of composite thermoelectric materials based on the eutectic phase relationship between PbTe and Ge. When quenched, these eutectic mixtures exhibit considerably stronger mechanical strength and reduced brittleness compared to PbTe itself, while at the same time they possess lower lattice thermal conductivity. Thermal conductivity measurements show values lower than expected based on the law of mixtures and multiphase composites. We find that the thermoelectric performance in these composites can be tuned through the use of hypereutectic compositions and alloying of Ge with Si. PbI2 was used as an n -type dopant, and precise control of the carrier concentration was achieved to optimize the electrical transport and thermoelectric properties. ZT values approaching 1.3 at 778 K have been obtained in samples of PbTe- Ge0.8 Si0.2 (5%), which represent an ∼62% improvement over that of PbTe.

Original languageEnglish
Article number083718
JournalJournal of Applied Physics
Volume105
Issue number8
DOIs
Publication statusPublished - 2009

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eutectic composites
figure of merit
mechanical properties
eutectics
composite materials
thermal conductivity
transport properties
brittleness
thermoelectric materials
alloying
microstructure
synthesis

ASJC Scopus subject areas

  • Physics and Astronomy(all)

Cite this

High thermoelectric figure of merit and improved mechanical properties in melt quenched PbTe-Ge and PbTe- Ge1-x Six eutectic and hypereutectic composites. / Sootsman, Joseph R.; He, Jiaqing; Dravid, Vinayak P.; Li, Chang Peng; Uher, Ctirad; Kanatzidis, Mercouri G.

In: Journal of Applied Physics, Vol. 105, No. 8, 083718, 2009.

Research output: Contribution to journalArticle

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